CO Adsorption on Thin MgO Films and Single Au Adatoms: A Scanning Tunneling Microscopy Study
文献类型：期刊论文
| 作者 | Yang, B ; Lin, X ; Gao, HJ ; Nilius, N ; Freund, HJ |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2010 |
| 卷号 | 114期号:19页码:8997 |
| 关键词 | OXIDE SURFACES VIBRATIONAL SPECTROSCOPY CARBON-MONOXIDE CLUSTER MODEL DEFECT SITES GOLD CHEMISTRY MGO(100) SPECTRA IDENTIFICATION |
| ISSN号 | 1932-7447 |
| 通讯作者 | Nilius, N: Max Planck Gesell, Fritz Haber Inst, Faradayweg 4-6, D-14195 Berlin, Germany. |
| 中文摘要 | The adsorption behavior of CO on a 2 ML thin MgO/Ag(001) film is investigated with scanning tunneling microscopy and spectroscopy at 5 K. Depending on the tip state, single CO molecules are imaged as Gaussian depressions or ring-like features on the oxide surface. The preferred CO adsorption sites are identified as the Mg(2+) positions next to an oxide step edge. The deposition of single Au atoms followed by CO exposure gives rise to the formation of monocarbonyl species on the MgO surface. Their vibrational properties are explored by inelastic electron-tunneling spectroscopy. The acquired second-derivative spectra are dominated by a symmetric peak/dip structure at +/-50 mV, which is assigned to the frustrated rotation of Au-bound CO molecules. |
| 收录类别 | SCI |
| 资助信息 | Cluster of Excellence (UNICAT); Deutsche Forschungsgemeinschaft |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/34759]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang, B,Lin, X,Gao, HJ,et al. CO Adsorption on Thin MgO Films and Single Au Adatoms: A Scanning Tunneling Microscopy Study[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2010,114(19):8997. |
| APA | Yang, B,Lin, X,Gao, HJ,Nilius, N,&Freund, HJ.(2010).CO Adsorption on Thin MgO Films and Single Au Adatoms: A Scanning Tunneling Microscopy Study.JOURNAL OF PHYSICAL CHEMISTRY C,114(19),8997. |
| MLA | Yang, B,et al."CO Adsorption on Thin MgO Films and Single Au Adatoms: A Scanning Tunneling Microscopy Study".JOURNAL OF PHYSICAL CHEMISTRY C 114.19(2010):8997. |
入库方式： OAI收割
来源：物理研究所
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