COORDINATION OF MOLECULAR NITROGEN AND HYDROGEN TO (ETA-6-C6H6)CR(CO)X AND (ETA-5-C5H5)MN(CO)X (X = 2 AND 1) IN THE GAS-PHASE
文献类型：期刊论文
| 作者 | ZHENG, YF ; WANG, WH ; LIN, JG ; SHE, YB ; FU, KJ |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY
 |
| 出版日期 | 1992 |
| 卷号 | 96期号:24页码:9821 |
| 关键词 | TRANSIENT INFRARED-SPECTROSCOPY TRANSITION-METAL COMPLEXES DIHYDROGEN COMPLEX SUPERCRITICAL FLUIDS ELECTRONIC-STRUCTURE ROOM-TEMPERATURE DINITROGEN CARBONYL LIGAND H-2 |
| ISSN号 | 0022-3654 |
| 中文摘要 | Time-resolved infrared absorption spectroscopy is used to study the coordination reactions of N2 and H-2 with photolytically generated coordinatively unsaturated species (eta6-C6H6)Cr(CO)x and (eta5-C5H5)Mn(CO)x (x = 2 and 1) in the gas phase. Additions of N2 and H-2 to (eta6-C6H6)Cr(CO)2 and (eta5-C5H5)Mn(CO)2 form corresponding molecular nitrogen and hydrogen complexes. Additions of N2 and H-2 to (eta6-C6H6)Cr(CO) are confirmed although no product absorption is observed. By comparison, reactions of N2 and H-2 with (eta5-C5H5)Mn(CO) are not observed, presumably due to spectral overlap. The rate constants for reactions of N2 and H-2 With (eta6-C6H6)Cr(CO)2 and (eta5-C5H5)Mn(CO)2 as well as with (eta6-C6H6)Cr(CO) are measured, and an upper limit for the rate constants for reactions of N2 and H-2 with (eta5-C5H5)Mn(CO) is estimated. Significant differences are observed for the rate constants for reactions of different species and discussed with respect to spin-allowed versus disallowed processes. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/35184]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | ZHENG, YF,WANG, WH,LIN, JG,et al. COORDINATION OF MOLECULAR NITROGEN AND HYDROGEN TO (ETA-6-C6H6)CR(CO)X AND (ETA-5-C5H5)MN(CO)X (X = 2 AND 1) IN THE GAS-PHASE[J]. JOURNAL OF PHYSICAL CHEMISTRY,1992,96(24):9821. |
| APA | ZHENG, YF,WANG, WH,LIN, JG,SHE, YB,&FU, KJ.(1992).COORDINATION OF MOLECULAR NITROGEN AND HYDROGEN TO (ETA-6-C6H6)CR(CO)X AND (ETA-5-C5H5)MN(CO)X (X = 2 AND 1) IN THE GAS-PHASE.JOURNAL OF PHYSICAL CHEMISTRY,96(24),9821. |
| MLA | ZHENG, YF,et al."COORDINATION OF MOLECULAR NITROGEN AND HYDROGEN TO (ETA-6-C6H6)CR(CO)X AND (ETA-5-C5H5)MN(CO)X (X = 2 AND 1) IN THE GAS-PHASE".JOURNAL OF PHYSICAL CHEMISTRY 96.24(1992):9821. |
入库方式： OAI收割
来源：物理研究所
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