中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Core-shell Fe3O4@SiO2 nanoparticles synthesized with well-dispersed hydrophilic Fe3O4 seeds

文献类型:期刊论文

作者Hui, C ; Shen, CM ; Tian, JF ; Bao, LH ; Ding, H ; Li, C ; Tian, YA ; Shi, XZ ; Gao, HJ
刊名NANOSCALE
出版日期2011
卷号3期号:2页码:701
关键词IRON-OXIDE NANOPARTICLES MAGNETIC-PROPERTIES FEPT NANOPARTICLES SURFACE-PROPERTIES SILICA PARTICLES SIZE NANOCRYSTALS HYDROLYSIS REACTIVITY TEMPLATES
ISSN号2040-3364
通讯作者Gao, HJ: Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China.
中文摘要Nanostructured diamond like carbon (DLC) thin films were fabricated by radio frequency sputtering and their electrochemical behavior as air electrodes for Li-air batteries were investigated for the first time. These nanostructured DLC air cathodes presented high discharge plateaus around 2.7 V and large reversible capacities around 2318 mAh/g at the current rate of 220 mA/g. The reaction mechanism of DLC thin film electrodes of lithium air cells was revealed by ex situ Raman, Fourier transform infrared (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED) measurements. The formation of nanocrystalline Li(2)O(2) and amorphous Li(2)CO(3) was confirmed in the discharge products. Our results have demonstrated that DLC thin films with sp(3)-bonded carbon atoms due to their good cyclic performance and low polarization between discharging and charging profiles exhibit a promising candidate of air electrode materials for future lithium air batteries. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3623431] All rights reserved.
收录类别SCI
资助信息National Natural Science Foundation of China [2007AA03Z305]; Key Technologies Research and Development Program of China
语种英语
公开日期2013-09-17
源URL[http://ir.iphy.ac.cn/handle/311004/35193]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Hui, C,Shen, CM,Tian, JF,et al. Core-shell Fe3O4@SiO2 nanoparticles synthesized with well-dispersed hydrophilic Fe3O4 seeds[J]. NANOSCALE,2011,3(2):701.
APA Hui, C.,Shen, CM.,Tian, JF.,Bao, LH.,Ding, H.,...&Gao, HJ.(2011).Core-shell Fe3O4@SiO2 nanoparticles synthesized with well-dispersed hydrophilic Fe3O4 seeds.NANOSCALE,3(2),701.
MLA Hui, C,et al."Core-shell Fe3O4@SiO2 nanoparticles synthesized with well-dispersed hydrophilic Fe3O4 seeds".NANOSCALE 3.2(2011):701.

入库方式: OAI收割

来源:物理研究所

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