Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis
文献类型:期刊论文
作者 | Guo, J ; Dong, C ; Yang, LH ; Fu, GC ; Chen, H |
刊名 | MATERIALS RESEARCH BULLETIN
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出版日期 | 2006 |
卷号 | 41期号:3页码:655 |
关键词 | HEXAGONAL TUNGSTEN BRONZE RAPID PREPARATION SUPERCONDUCTING PROPERTIES TEMPERATURE CONDUCTION CERAMICS PHASES OVEN |
ISSN号 | 0025-5408 |
通讯作者 | Guo, J: Chinese Acad Sci, Inst Phys, Natl Lab Superconduct, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | Calcium tungsten bronzes CaxWO3 (0.01 <= x <= 0.15) were synthesized by hybrid microwave method from mixtures of CaO, WO3 and tungsten powder. Single-phased samples can be obtained by microwave heating within 40 min. With the increase of calcium content, the crystal structure of CaxWO3 transforms from orthorhombic (0.01 <= x <= 0.02) to tetragonal (0.03 <= x <= 0.11) and then to cubic (0.12 <= x <= 0.15). The average size of crystallites is in the range 1-5 mu m. All samples show semiconductor behaviour in their temperature dependence of resistivity. The electrical conduction mechanism changes from variable-range hopping to the thermally activated mechanism when x > 0.12. (c) 2005 Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/35344] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Guo, J,Dong, C,Yang, LH,et al. Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis[J]. MATERIALS RESEARCH BULLETIN,2006,41(3):655. |
APA | Guo, J,Dong, C,Yang, LH,Fu, GC,&Chen, H.(2006).Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis.MATERIALS RESEARCH BULLETIN,41(3),655. |
MLA | Guo, J,et al."Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis".MATERIALS RESEARCH BULLETIN 41.3(2006):655. |
入库方式: OAI收割
来源:物理研究所
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