中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis

文献类型:期刊论文

作者Guo, J ; Dong, C ; Yang, LH ; Fu, GC ; Chen, H
刊名MATERIALS RESEARCH BULLETIN
出版日期2006
卷号41期号:3页码:655
关键词HEXAGONAL TUNGSTEN BRONZE RAPID PREPARATION SUPERCONDUCTING PROPERTIES TEMPERATURE CONDUCTION CERAMICS PHASES OVEN
ISSN号0025-5408
通讯作者Guo, J: Chinese Acad Sci, Inst Phys, Natl Lab Superconduct, POB 603, Beijing 100080, Peoples R China.
中文摘要Calcium tungsten bronzes CaxWO3 (0.01 <= x <= 0.15) were synthesized by hybrid microwave method from mixtures of CaO, WO3 and tungsten powder. Single-phased samples can be obtained by microwave heating within 40 min. With the increase of calcium content, the crystal structure of CaxWO3 transforms from orthorhombic (0.01 <= x <= 0.02) to tetragonal (0.03 <= x <= 0.11) and then to cubic (0.12 <= x <= 0.15). The average size of crystallites is in the range 1-5 mu m. All samples show semiconductor behaviour in their temperature dependence of resistivity. The electrical conduction mechanism changes from variable-range hopping to the thermally activated mechanism when x > 0.12. (c) 2005 Elsevier Ltd. All rights reserved.
收录类别SCI
语种英语
公开日期2013-09-17
源URL[http://ir.iphy.ac.cn/handle/311004/35344]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Guo, J,Dong, C,Yang, LH,et al. Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis[J]. MATERIALS RESEARCH BULLETIN,2006,41(3):655.
APA Guo, J,Dong, C,Yang, LH,Fu, GC,&Chen, H.(2006).Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis.MATERIALS RESEARCH BULLETIN,41(3),655.
MLA Guo, J,et al."Crystal structure and electrical properties of CaxWO3 (0.01 <= x <= 0.15) prepared by hybrid microwave synthesis".MATERIALS RESEARCH BULLETIN 41.3(2006):655.

入库方式: OAI收割

来源:物理研究所

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