Crystal structure and Eu3+/Tb3+ doped luminescent properties of a new borate Ba3BiB9O18
文献类型：期刊论文
| 作者 | Cai, GM ; Li, M ; Liu, J ; Jin, SF ; Wang, WY ; Zheng, F ; Chen, XL |
| 刊名 | MATERIALS RESEARCH BULLETIN
 |
| 出版日期 | 2009 |
| 卷号 | 44期号:12页码:2211 |
| ISSN号 | 0025-5408 |
| 关键词 | NONLINEAR-OPTICAL CRYSTAL PHASE-RELATIONS VUV EXCITATION SYSTEM PHOTOLUMINESCENCE BIB3O6 YB TM HO UV |
| 通讯作者 | Chen, XL: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | Undoped and doped either by Eu3+ or Tb3+ bismuth borate Ba3BiB9O18 was structurally characterized and analyzed by fluorescence spectroscopy. Belonging to synthetic borate member of the family Ba3XB9O18, layers of planar triangular B3O6 groups connecting with deformed BaO6 hexagons are interleaved by 9-coordinate Ba atoms, and 6-coordinate Bi atoms. Its crystal structure was determined and refined from powder X-ray diffraction data by the Rietveld method and the results showed that Ba3BiB9O18 belongs to space group P6(3)/m with unit cell dimensions of a = 7.1999(2) angstrom, c = 17.3567(6) angstrom, and z = 2. Curves of differential thermal analysis and thermogravimetric analysis showed that Ba3BiB9O18 is a congruent melting compound and chemically stable above 728 degrees C. Ba3Bi1-xEuxB9O18 and Ba3Bi1-xTbxB9O18 form a continuous solid solution from x = 0.01 to x = 0.9. The ultraviolet excited photoluminescence intensity increased with both Eu3+ and Tb3+ concentration in the matrix of Ba3BiB9O18. There may be an interesting correlation between spectroscopic properties and lattice structural features of doped Ba3BiB9O18. (C) 2009 Elsevier Ltd. All rights reserved. |
| 资助信息 | National Natural Science Foundation of China [50632070, 50872144]; Central South University [761320470]; International Centre for Diffraction Data (ICDD) |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/35348]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cai, GM,Li, M,Liu, J,et al. Crystal structure and Eu3+/Tb3+ doped luminescent properties of a new borate Ba3BiB9O18[J]. MATERIALS RESEARCH BULLETIN,2009,44(12):2211. |
| APA | Cai, GM.,Li, M.,Liu, J.,Jin, SF.,Wang, WY.,...&Chen, XL.(2009).Crystal structure and Eu3+/Tb3+ doped luminescent properties of a new borate Ba3BiB9O18.MATERIALS RESEARCH BULLETIN,44(12),2211. |
| MLA | Cai, GM,et al."Crystal structure and Eu3+/Tb3+ doped luminescent properties of a new borate Ba3BiB9O18".MATERIALS RESEARCH BULLETIN 44.12(2009):2211. |
入库方式： OAI收割
来源：物理研究所
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