Crystallographic and magnetic properties of the hydrides R3Fe29-xCrxHy (R = Y, Ce, Nd, Sm, Gd, Tb, and Dy)
文献类型:期刊论文
作者 | Han, XF ; Xu, RG ; Wang, XH ; Pan, HG ; Miyazaki, T ; Baggio-Saitovitch, E ; Yang, FM ; Cheng, CP |
刊名 | JOURNAL OF PHYSICS-CONDENSED MATTER
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出版日期 | 1998 |
卷号 | 10期号:31页码:7037 |
关键词 | TERNARY PHASE CR NITRIDES CRYSTAL SYSTEM T=TI R=Y MN |
ISSN号 | 0953-8984 |
通讯作者 | Han, XF: Chinese Acad Sci, Inst Semicond, Ctr Mat Sci, POB 912, Beijing 100083, Peoples R China. |
中文摘要 | A systematic study of the structural and intrinsic magnetic properties of the hydrides R3Fe29-xCrxHy (R = Y, Ce, Nd, Sm, Gd, Tb, and Dy) has been performed. Hydrogenation lends to a relative volume expansion of the unit cell and a decrease in x-ray density for each compound. Anisotropic expansions mainly along the n- and b-axes rather than along the c-axis for all of the compounds upon hydrogenation are observed. The lattice constants and the unit-cell volume of R3Fe29-xCrx and R3Fe29-xCrxHy decrease with increasing R atomic number from Nd to Dy, except for Ce, reflecting the lanthanide contraction. Hydrogenation results in an increase in the Curie temperature and a corresponding increase in the saturation magnetization at room temperature for each compound. After hydrogenation a decrease of 0.34 mu(B)/Fe in the average Fe atomic magnetic moment and a slight increase in the anisotropy field for Y3Fe27.2Cr1.8 are achieved at 4.2 K. First-order magnetization processes (FOMP) occur in magnetic fields of around 1.5 T and 4.0 T at 4.2 K for Nd3Fe24.5Cr4.5H5.0 and TD3Fe27.0Cr2.0H2.8, and around 1.4 T at room temperature for Gd3Fe28.0Cr1.0H4.2. The abnormal crystallographic and magnetic properties of Ce3Fe25.0Cr4.0 and Ce3Fe25.0Cr4.0H5.4 suggest that the Ce ion non-triply ionized. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/35470] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Han, XF,Xu, RG,Wang, XH,et al. Crystallographic and magnetic properties of the hydrides R3Fe29-xCrxHy (R = Y, Ce, Nd, Sm, Gd, Tb, and Dy)[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,1998,10(31):7037. |
APA | Han, XF.,Xu, RG.,Wang, XH.,Pan, HG.,Miyazaki, T.,...&Cheng, CP.(1998).Crystallographic and magnetic properties of the hydrides R3Fe29-xCrxHy (R = Y, Ce, Nd, Sm, Gd, Tb, and Dy).JOURNAL OF PHYSICS-CONDENSED MATTER,10(31),7037. |
MLA | Han, XF,et al."Crystallographic and magnetic properties of the hydrides R3Fe29-xCrxHy (R = Y, Ce, Nd, Sm, Gd, Tb, and Dy)".JOURNAL OF PHYSICS-CONDENSED MATTER 10.31(1998):7037. |
入库方式: OAI收割
来源:物理研究所
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