Electrochemical characterization of positive electrode material LiNi1/3Co1/3Mn1/3O2 and compatibility with electrolyte for lithium-ion batteries
文献类型：期刊论文
| 作者 | Wang, ZX ; Sun, YC ; Chen, LQ ; Huang, XJ |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 2004 |
| 卷号 | 151期号:6页码:A914 |
| 关键词 | STATE REDOX REACTIONS X-RAY-DIFFRACTION CATHODE MATERIALS PROPYLENE CARBONATE INSERTION MATERIAL LICOO2 CATHODE SURFACE-FILMS CELLS LI PERFORMANCE |
| ISSN号 | 0013-4651 |
| 通讯作者 | Wang, ZX: Chinese Acad Sci, Inst Phys, Lab Solid State Ion, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | Positive electrode materials LiCoO2, commercial and nanosized, bare and Al2O3-coated, are soaked in a mixture of battery-grade ethylene carbonate and dimethyl carbonate, with and without LiPF6. Strong spontaneous reactions have been observed between LiCoO2 and the solvent. These reactions become less obvious in practical electrolyte. The composition of the soakage-induced.as, liquid, and solid products are characterized with gas chromatography and mass spectroscopy, Raman and Fourier transformed infrared spectroscopy, respectively. The atomic ratios of Co/Li in the liquid and in the solid are analyzed by inductively coupled plasma technique. The surface morphologies of the solvent- and electrolyte-soaked commercial LiCoO2 particles are observed with scanning electron microscopy. Significant impacts of the spontaneous reactions on the structure and electrochemical performance of the electrode material are evaluated with X-ray diffraction (XRD) and electrochemical cycling, respectively. Based on these results, other important aspects of the performance improvement mechanism by surface modification to LiCoO2 and the limitation of surface modification are proposed. (C) 2004 The Electrochemical Society. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/36995]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, ZX,Sun, YC,Chen, LQ,et al. Electrochemical characterization of positive electrode material LiNi1/3Co1/3Mn1/3O2 and compatibility with electrolyte for lithium-ion batteries[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2004,151(6):A914. |
| APA | Wang, ZX,Sun, YC,Chen, LQ,&Huang, XJ.(2004).Electrochemical characterization of positive electrode material LiNi1/3Co1/3Mn1/3O2 and compatibility with electrolyte for lithium-ion batteries.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,151(6),A914. |
| MLA | Wang, ZX,et al."Electrochemical characterization of positive electrode material LiNi1/3Co1/3Mn1/3O2 and compatibility with electrolyte for lithium-ion batteries".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 151.6(2004):A914. |
入库方式： OAI收割
来源：物理研究所
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