中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical properties of TiP2O7 and LiTi2(PO4)(3) as anode material for lithium ion battery with aqueous solution electrolyte

文献类型:期刊论文

作者Wang, HB ; Huang, KL ; Zeng, YQ ; Yang, S ; Chen, LQ
刊名ELECTROCHIMICA ACTA
出版日期2007
卷号52期号:9页码:3280
关键词SECONDARY BATTERIES LIMN2O4 CELLS
ISSN号0013-4686
通讯作者Chen, LQ: Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China.
中文摘要Some polyanionic compounds, e.g. TiP2O7 and LiTi2(PO4)(3) with 3D framework structure were proposed to be used as anodes of lithium ion battery with aqueous electrolyte. The cyclic voltammetry properties TiP2O7 and LiTi2(PO4)(3) suggested that Li-ion de/intercalation reaction can occur without serious hydrogen evolution in 5 M LiNO3 aqueous solution. The TiP2O7 and LiTi2(PO4)(3) give capacities of about 80 mAh/g between potentials of -0.50 V and 0 V (versus SHE) and 90 mAh/g between -0.65 V and -0.10 V (versus SHE), respectively. A test cell consisting of TiP2O7/5 M LiNO3/LiMn2O4 delivers approximately 42 mAh/g (weight of cathodeand anode) at average voltage of 1.40 V, and LiTi2(PO4)(3)/5 M LiNO3/LiMn2O4 delivers approximately 45 mAh/g at average voltage of 1.50 V. Both as-assembled cells suffered from short cycle life. The capacity fading may be related to deterioration of anode material. (c) 2006 Elsevier Ltd. All rights reserved.
收录类别SCI
语种英语
公开日期2013-09-17
源URL[http://ir.iphy.ac.cn/handle/311004/37012]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Wang, HB,Huang, KL,Zeng, YQ,et al. Electrochemical properties of TiP2O7 and LiTi2(PO4)(3) as anode material for lithium ion battery with aqueous solution electrolyte[J]. ELECTROCHIMICA ACTA,2007,52(9):3280.
APA Wang, HB,Huang, KL,Zeng, YQ,Yang, S,&Chen, LQ.(2007).Electrochemical properties of TiP2O7 and LiTi2(PO4)(3) as anode material for lithium ion battery with aqueous solution electrolyte.ELECTROCHIMICA ACTA,52(9),3280.
MLA Wang, HB,et al."Electrochemical properties of TiP2O7 and LiTi2(PO4)(3) as anode material for lithium ion battery with aqueous solution electrolyte".ELECTROCHIMICA ACTA 52.9(2007):3280.

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来源:物理研究所

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