Facile route to metal nitrides through melamine and metal oxides
文献类型：期刊论文
| 作者 | Zhao, HZ ; Lei, M ; Chen, XL ; Tang, WH |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2006 |
| 卷号 | 16期号:45页码:4407 |
| 关键词 | SOLID-STATE PRECURSORS METATHESIS REACTIONS CRYSTAL-STRUCTURES CARBOTHERMAL REDUCTION ALUMINUM NITRIDE TRANSITION-METAL CARBON NITRIDE GAN COATINGS CERAMICS |
| ISSN号 | 0959-9428 |
| 通讯作者 | Chen, XL: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | Highly efficient and facile routes are still needed to meet the increasing demand on nitrides in a variety of applications although so far some preparative routes already exist. We have extended the solid-state metathesis (SSM) method by choosing an organic compound, melamine, and oxides as precursors, which allows us to develop a relatively general and facile route to nitrides. Whereby, eight technologically important nitrides including hexagonal GaN and cubic TiN were synthesized in sealed ampoules. These reactions are dynamically facilitated by the formation of numerous interfaces between finely-divided oxide grains and gas phases with high reactivity in an intermediate stage under heating temperatures. It is found that both hydrogen and carbon reductions are involved in the reactions, thermodynamically enhancing the nitride formation process. Our results demonstrate that the reactions between an organic compound and oxides offer an attractive preparative route to nitrides in terms of the wide availability of reagents, high yield and relative generality. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/37974]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao, HZ,Lei, M,Chen, XL,et al. Facile route to metal nitrides through melamine and metal oxides[J]. JOURNAL OF MATERIALS CHEMISTRY,2006,16(45):4407. |
| APA | Zhao, HZ,Lei, M,Chen, XL,&Tang, WH.(2006).Facile route to metal nitrides through melamine and metal oxides.JOURNAL OF MATERIALS CHEMISTRY,16(45),4407. |
| MLA | Zhao, HZ,et al."Facile route to metal nitrides through melamine and metal oxides".JOURNAL OF MATERIALS CHEMISTRY 16.45(2006):4407. |
入库方式： OAI收割
来源：物理研究所
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