Far-infrared study of the insulator-metal transition in theta-(BEDT-TTF)(2)RbZn(SCN)(4) (BEDT-TTF equivalent to bis (ethylene-dithio)tetrathiafulvalene)
文献类型:期刊论文
作者 | Wang, NL ; Mori, H ; Tanaka, S ; Dong, J ; Clayman, BP |
刊名 | JOURNAL OF PHYSICS-CONDENSED MATTER
![]() |
出版日期 | 2001 |
卷号 | 13期号:23页码:5463 |
关键词 | ORGANIC CONDUCTORS SUPERCONDUCTOR SALTS |
ISSN号 | 0953-8984 |
通讯作者 | Wang, NL: Chinese Acad Sci, Inst Phys, POB 2711, Beijing 100080, Peoples R China. |
中文摘要 | We investigated the temperature-dependent infrared properties of the compound theta-(BEDT-TTF)(2)RbZn(SCN)(4). At temperatures above the metal-insulator transition, the optical conductivity remains finite in the low-energy region, but shows no conventional Drude feature typical of metals. Below the metal-insulator transition temperature, the low-energy spectral weight is significantly reduced. The opening of an optical gap at about 300 cm(-1) is observed clearly in polarization parallel to the donor stacking direction. Analysis of both the electronic and vibronic spectra suggests a redistribution of charges in BEDT-TTF molecules as temperature decreases across the metal-insulator transition, providing strong support for a charge-ordering state at low temperatures. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/38005] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Wang, NL,Mori, H,Tanaka, S,et al. Far-infrared study of the insulator-metal transition in theta-(BEDT-TTF)(2)RbZn(SCN)(4) (BEDT-TTF equivalent to bis (ethylene-dithio)tetrathiafulvalene)[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2001,13(23):5463. |
APA | Wang, NL,Mori, H,Tanaka, S,Dong, J,&Clayman, BP.(2001).Far-infrared study of the insulator-metal transition in theta-(BEDT-TTF)(2)RbZn(SCN)(4) (BEDT-TTF equivalent to bis (ethylene-dithio)tetrathiafulvalene).JOURNAL OF PHYSICS-CONDENSED MATTER,13(23),5463. |
MLA | Wang, NL,et al."Far-infrared study of the insulator-metal transition in theta-(BEDT-TTF)(2)RbZn(SCN)(4) (BEDT-TTF equivalent to bis (ethylene-dithio)tetrathiafulvalene)".JOURNAL OF PHYSICS-CONDENSED MATTER 13.23(2001):5463. |
入库方式: OAI收割
来源:物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。