FT-Raman spectroscopic and density functional theory studies on ion preferential solvation and ion association of lithium tetrafluoroborate in 4-methoxymethyl ethylene carbonate-based mixed solvents
文献类型：期刊论文
| 作者 | Qiao, HW ; Luan, HL ; Fang, XP ; Zhou, ZM ; Yao, W ; Wang, X ; Li, JM ; Chen, C ; Tian, Y |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2008 |
| 卷号 | 878期号:1-3页码:185 |
| ISSN号 | 0022-2860 |
| 中文摘要 | Using hexamethyldisiloxane (HMDSO) monomer, the magnetic nanoparticles (NPs) of nickel oxide (NiO) were modified by using an atmospheric room-temperature plasma fluidized bed (ARPFB). The plasma gas temperature of the ARPFB was not higher than 325 K, which was favorable for organic polymerization. The plasma optical emission spectrum (OES) of the gas mixture consisting of argon (Ar) and HMDSO was recorded by a UV-visible monochromator. The as-treated NPs were characterized by means of scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The results show that the assembling NPs were isolated greatly after modified by the organosilicon polymer. Moreover, this treatment process changed the wettability of the NPs from super-hydrophilicity to super-hydrophobicity, and the contact angle (CA) of water on the modified NPs surface exceeded 1508. Therefore, the ARPFB is a prospective technology for the NPs surface modification according to the different requirements. (C) 2007 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/38502]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qiao, HW,Luan, HL,Fang, XP,et al. FT-Raman spectroscopic and density functional theory studies on ion preferential solvation and ion association of lithium tetrafluoroborate in 4-methoxymethyl ethylene carbonate-based mixed solvents[J]. JOURNAL OF MOLECULAR STRUCTURE,2008,878(1-3):185. |
| APA | Qiao, HW.,Luan, HL.,Fang, XP.,Zhou, ZM.,Yao, W.,...&Tian, Y.(2008).FT-Raman spectroscopic and density functional theory studies on ion preferential solvation and ion association of lithium tetrafluoroborate in 4-methoxymethyl ethylene carbonate-based mixed solvents.JOURNAL OF MOLECULAR STRUCTURE,878(1-3),185. |
| MLA | Qiao, HW,et al."FT-Raman spectroscopic and density functional theory studies on ion preferential solvation and ion association of lithium tetrafluoroborate in 4-methoxymethyl ethylene carbonate-based mixed solvents".JOURNAL OF MOLECULAR STRUCTURE 878.1-3(2008):185. |
入库方式： OAI收割
来源：物理研究所
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