Generalized Holstein model for spin-dependent electron-transfer reactions
文献类型：期刊论文
| 作者 | Yang, LP ; Ai, Q ; Sun, CP |
| 刊名 | PHYSICAL REVIEW A
 |
| 出版日期 | 2012 |
| 卷号 | 85期号:3 |
| 关键词 | MAGNETORECEPTION COHERENCE MECHANISM MOTION SALTS BIRDS |
| ISSN号 | 1050-2947 |
| 通讯作者 | Yang, LP: Chinese Acad Sci, State Key Lab Theoret Phys, Inst Theoret Phys, Beijing 100190, Peoples R China. |
| 中文摘要 | Some chemical reactions are described by electron transfer (ET) processes. The underlying mechanism could be modeled as a polaron motion in the molecular crystal-the Holstein model. By taking spin degrees of freedom into consideration, we generalize the Holstein model (molecular crystal model) to microscopically describe an ET chemical reaction. In our model, the electron spins in the radical pair simultaneously interact with a magnetic field and their nuclear-spin environments. By virtue of the perturbation approach, we obtain the chemical reaction rates for different initial states. It is discovered that the chemical reaction rate of the triplet state demonstrates its dependence on the direction of the magnetic field while the counterpart of the singlet state does not. This difference is attributed to the explicit dependence of the triplet state on the direction when the axis is rotated. Our model may provide a possible candidate for the microscopic origin of the avian compass. |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [10935010, 11074261] |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/38618]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang, LP,Ai, Q,Sun, CP. Generalized Holstein model for spin-dependent electron-transfer reactions[J]. PHYSICAL REVIEW A,2012,85(3). |
| APA | Yang, LP,Ai, Q,&Sun, CP.(2012).Generalized Holstein model for spin-dependent electron-transfer reactions.PHYSICAL REVIEW A,85(3). |
| MLA | Yang, LP,et al."Generalized Holstein model for spin-dependent electron-transfer reactions".PHYSICAL REVIEW A 85.3(2012). |
入库方式： OAI收割
来源：物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。