H-2 production from stable ethanol steam reforming over catalyst of NiO based on flowerlike CeO2 microspheres
文献类型:期刊论文
作者 | Sun, J ; Wang, YG ; Li, JG ; Xiao, GL ; Zhang, LG ; Li, H ; Cheng, YL ; Sun, CW ; Cheng, ZX ; Dong, ZC ; Chen, LQ |
刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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出版日期 | 2010 |
卷号 | 35期号:7页码:3087 |
关键词 | FUEL-CELL APPLICATION LOW-TEMPERATURE HYDROGEN CERIA OXIDATION NI/Y2O3 |
ISSN号 | 0360-3199 |
通讯作者 | Sun, J: Inst Chem Def, Lab Renewable Energy & Energy Safety, Beijing 102205, Peoples R China. |
中文摘要 | Catalyst of nickle oxide based on flowerlike cerium microspheres with high dispersion was made to achieve simultaneous dehydrogenation of ethanol and water molecules on multi-active sites. XRD, 77 K N-2 adsorption and FESEM were applied to analyse and observe the catalyst's structure, porosity and morphology. This special morphology catalyst represented novel stability more than 600 h for hydrogen production at low temperature ethanol steam reforming. Ethanol-water mixtures could be converted into H-2 with average selectivity value of 61.5 mol.% and average ethanol conversion 95.0 mol.% at 350 degrees C, with GHSV similar to 1.0 x 10(5) h(-1), low CO selectivity about average value of 2.1 mol.%, during 550 h reforming stability test. Catalytic parameters with respect to yield of H-2, activity, selectivity towards hydrogen production and stability with time on stream were determined. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/39036] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Sun, J,Wang, YG,Li, JG,et al. H-2 production from stable ethanol steam reforming over catalyst of NiO based on flowerlike CeO2 microspheres[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2010,35(7):3087. |
APA | Sun, J.,Wang, YG.,Li, JG.,Xiao, GL.,Zhang, LG.,...&Chen, LQ.(2010).H-2 production from stable ethanol steam reforming over catalyst of NiO based on flowerlike CeO2 microspheres.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,35(7),3087. |
MLA | Sun, J,et al."H-2 production from stable ethanol steam reforming over catalyst of NiO based on flowerlike CeO2 microspheres".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35.7(2010):3087. |
入库方式: OAI收割
来源:物理研究所
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