High rate delithiation behaviour of LiFePO4 studied by quick X-ray absorption spectroscopy
文献类型：期刊论文
| 作者 | Yu, XQ ; Wang, Q ; Zhou, YN ; Li, H ; Yang, XQ ; Nam, KW ; Ehrlich, SN ; Khalid, S ; Meng, YS |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2012 |
| 卷号 | 48期号:94页码:11537 |
| 关键词 | POSITIVE-ELECTRODE MATERIALS LI-ION BATTERIES SINGLE-CRYSTALS LITHIUM BATTERIES SOLID-SOLUTION KINETICS FE LIXFEPO4 MN |
| ISSN号 | 1359-7345 |
| 通讯作者 | Yang, XQ: Brookhaven Natl Lab, Upton, NY 11973 USA. |
| 中文摘要 | In this paper, we provide a method for the simultaneous measurement of the inner diameter of nanotubes with a regular shape and calculation of their mean inner potential (MIP) using electron holography. This method contains 4 steps: (i) phase profile characterization from electron holography; (ii) shape assumption from prepared data; (iii) thickness simulation from a shape assumption and fitting method; (iv) calculation of MIP of the simulated and fitted parameters. By this method, as an example, the shape and the outer and inner diameters of a tube formed from C-60 molecules were characterized. The MIP of the tube was also calculated through this method. The MIP calculation from another nano whisker formed from C-60 molecules supports the feasibility of our method and it could be extended to other nanomaterials. This work provides a convenient method for morphology characterization of hollow nanomaterials, such as diameter measurements and cross-sectional shape determination, which are the most basic and important characteristics of the nanomaterials. In addition, it also provides a method for MIP calculation without a thickness measurement if the samples have relatively regular shapes. Thus this method should be more convenient for closely combining the tomography and physical properties of samples, which could be essential for in situ TEM studies of nanomaterials. |
| 收录类别 | SCI |
| 资助信息 | Northeastern Center for Chemical Energy Storage, an Energy Frontier Research Center; U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001294] |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/39237]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yu, XQ,Wang, Q,Zhou, YN,et al. High rate delithiation behaviour of LiFePO4 studied by quick X-ray absorption spectroscopy[J]. CHEMICAL COMMUNICATIONS,2012,48(94):11537. |
| APA | Yu, XQ.,Wang, Q.,Zhou, YN.,Li, H.,Yang, XQ.,...&Meng, YS.(2012).High rate delithiation behaviour of LiFePO4 studied by quick X-ray absorption spectroscopy.CHEMICAL COMMUNICATIONS,48(94),11537. |
| MLA | Yu, XQ,et al."High rate delithiation behaviour of LiFePO4 studied by quick X-ray absorption spectroscopy".CHEMICAL COMMUNICATIONS 48.94(2012):11537. |
入库方式： OAI收割
来源：物理研究所
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