High-Pressure Synthesis, Crystal Structure, and Electromagnetic Properties of CdRh2O4: an Analogous Oxide of the Postspinel Mineral M9Al2O4
文献类型：期刊论文
| 作者 | Wang, X ; Guo, YF ; Shi, YG ; Belik, AA ; Tsujimoto, Y ; Yi, W ; Sun, Y ; Shirako, Y ; Arai, M ; Akaogi, M ; Matsushita, Y ; Yamaura, K |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 51期号:12页码:6868 |
| 关键词 | SUBDUCTED BASALTIC CRUST EARTHS LOWER MANTLE PHASE-TRANSFORMATIONS SPINEL PEROVSKITE GPA DISCONTINUITY TRANSITIONS FORSTERITE CAFE2O4 |
| ISSN号 | 0020-1669 |
| 通讯作者 | Guo, YF: Natl Inst Mat Sci, Superconducting Properties Unit, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan. |
| 中文摘要 | The postspinel mineral MgAl2O4 exists only under the severe pressure conditions in the subducted oceanic lithosphere in the Earth's deep interior. Here we report that its analogous oxide CdRh2O4 exhibits a structural transition to a quenchable postspinel phase under a high pressure of 6 GPa at 1400 degrees C, which is within the general pressure range of a conventional single-stage multianvil system. In addition, the complex magnetic contributions to the lattice and metal nonstoichiometry that often complicate investigations of other analogues of MgAl2O4 are absent in CdRh2O4. X-ray crystallography revealed that this postspinel phase has an orthorhombic CaFe2O4 structure, thus making it a practical analogue for investigations into the geophysical role of postspinel MgAl2O4. Replacement of Mg2+ with Cd2+ appears to be effective in lowering the pressure required for transition, as was suggested for CdGeO3. In addition, Rh3+ could also contribute to this reduction, as many analogous Rh oxides of aluminous and silicic minerals have been quenched. from lower-pressure conditions. |
| 收录类别 | SCI |
| 资助信息 | World Premier International Research Center from MEXT; JSPS [22246083]; JST |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/39407]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, X,Guo, YF,Shi, YG,et al. High-Pressure Synthesis, Crystal Structure, and Electromagnetic Properties of CdRh2O4: an Analogous Oxide of the Postspinel Mineral M9Al2O4[J]. INORGANIC CHEMISTRY,2012,51(12):6868. |
| APA | Wang, X.,Guo, YF.,Shi, YG.,Belik, AA.,Tsujimoto, Y.,...&Yamaura, K.(2012).High-Pressure Synthesis, Crystal Structure, and Electromagnetic Properties of CdRh2O4: an Analogous Oxide of the Postspinel Mineral M9Al2O4.INORGANIC CHEMISTRY,51(12),6868. |
| MLA | Wang, X,et al."High-Pressure Synthesis, Crystal Structure, and Electromagnetic Properties of CdRh2O4: an Analogous Oxide of the Postspinel Mineral M9Al2O4".INORGANIC CHEMISTRY 51.12(2012):6868. |
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来源：物理研究所
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