Homochiral Recognition among Organic Molecules on Copper(110)
文献类型:期刊论文
作者 | Cun, HY ; Wang, YL ; Yang, B ; Zhang, L ; Du, SX ; Wang, Y ; Ernst, KH ; Gao, HJ |
刊名 | LANGMUIR
![]() |
出版日期 | 2010 |
卷号 | 26期号:5页码:3402 |
关键词 | SCANNING-TUNNELING-MICROSCOPY CHIRAL PHASE-TRANSITION QUINACRIDONE DERIVATIVES SPONTANEOUS RESOLUTION CU(110) SURFACES TARTARIC ACID AMINO-ACIDS MONOLAYERS CRYSTALS DISCRIMINATION |
ISSN号 | 0743-7463 |
通讯作者 | Ernst, KH: Empa, Swiss Fed Labs Mat Testing & Res, Uberlandstr 129, CH-8600 Dubendorf, Switzerland. |
中文摘要 | The adsorption of a prochiral quinacridone derivative (QA16C) with two alkyl chains of 16 carbon atoms on a Cu(110) surface wits investigated with scanning tunneling microscopy. QA16C molecules prefer to assemble at 150 K into short homochiral molecular lines with two enantiomorphous orientations in which the lateral alkyl chains exhibit partial disorder. With increasing S sample temperatures, the QA16C lines form larger well-ordered homochiral domains. As a reason for the homochiral recognition, we identify a rigid alignment of the molecule due to the interaction with the substraw. In addition, lateral intermolecular interactions in the form of hydrogen bonding and van der Waals interactions are identified. |
收录类别 | SCI |
资助信息 | NSFC [10674159, 10874219]; Swiss National Science Foundation (SNSF) |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/39482] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Cun, HY,Wang, YL,Yang, B,et al. Homochiral Recognition among Organic Molecules on Copper(110)[J]. LANGMUIR,2010,26(5):3402. |
APA | Cun, HY.,Wang, YL.,Yang, B.,Zhang, L.,Du, SX.,...&Gao, HJ.(2010).Homochiral Recognition among Organic Molecules on Copper(110).LANGMUIR,26(5),3402. |
MLA | Cun, HY,et al."Homochiral Recognition among Organic Molecules on Copper(110)".LANGMUIR 26.5(2010):3402. |
入库方式: OAI收割
来源:物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。