Hydrogen storage properties of Mg-Ce-Ni nanocomposite induced from amorphous precursor with the highest Mg content
文献类型：期刊论文
| 作者 | Lin, HJ ; Ouyang, LZ ; Wang, H ; Zhao, DQ ; Wang, WH ; Sun, DL ; Zhu, M |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2012 |
| 卷号 | 37期号:19页码:14329 |
| 关键词 | X-RAY-DIFFRACTION IN-SITU SYNCHROTRON MELT-SPUN ALLOYS MAGNESIUM PHASE MICROSTRUCTURE TRANSITION KINETICS BEHAVIOR |
| ISSN号 | 0360-3199 |
| 通讯作者 | Zhu, M: S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Peoples R China. |
| 中文摘要 | The effect of Ce and Ni contents on the glass-forming ability (GFA) of Mg-Ce-Ni system in the Mg-rich corner of Mg-Ce-Ni system is revealed. Ce is more advantageous for the GFA of Mg-rich Mg-Ce-Ni system than Ni, and the lowest Ce content is similar to 5 at.% to obtain the fully amorphous alloy. Amorphous alloy with the highest Mg content, Mg90Ce5Ni5, was obtained by melt-spinning. With the amorphous alloy as precursor, nanostructure multi-phases compositae was prepared by crystallizing it in hydrogenation process. The compositae with reversible hydrogen storage capacity of 5.3 wt.% shows much faster kinetics and lower MgH2 desorption activation energy than those of induction-melt Mg90Ce5Ni5 alloy. Both in situ formed nanosized Mg2Ni and CeH2.73 act as effective catalysts and significantly improve the hydrogen storage properties of MgH2. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 资助信息 | MOST 973 [2010CB631302, 2007CB613904]; NSF of China [50731008, 50921091, 50971061] |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/39536]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin, HJ,Ouyang, LZ,Wang, H,et al. Hydrogen storage properties of Mg-Ce-Ni nanocomposite induced from amorphous precursor with the highest Mg content[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2012,37(19):14329. |
| APA | Lin, HJ.,Ouyang, LZ.,Wang, H.,Zhao, DQ.,Wang, WH.,...&Zhu, M.(2012).Hydrogen storage properties of Mg-Ce-Ni nanocomposite induced from amorphous precursor with the highest Mg content.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,37(19),14329. |
| MLA | Lin, HJ,et al."Hydrogen storage properties of Mg-Ce-Ni nanocomposite induced from amorphous precursor with the highest Mg content".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 37.19(2012):14329. |
入库方式： OAI收割
来源：物理研究所
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