Hydrogenation, structure and magnetic properties of La(Fe0.91Si0.09)(13) hydrides and deuterides
文献类型:期刊论文
作者 | Wang, ZC ; He, LH ; Cuevas, F ; Latroche, M ; Shen, J ; Wang, FW |
刊名 | CHINESE PHYSICS B
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出版日期 | 2011 |
卷号 | 20期号:6 |
关键词 | ENTROPY CHANGE COMPOUND LAFE11.4SI1.6 TEMPERATURE |
ISSN号 | 1674-1056 |
通讯作者 | Wang, FW: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China. |
中文摘要 | Hydrogenation, crystal structure and magnetic properties of La(Fe0.91Si0.09)(13)H(D)(y) have been studied by pressure-composition isotherms (PCI), X-ray diffraction (XRD), differential scanning calorimetry (DSC) and magnetization measurements. The maximum absorption capacity is found to be 1.9 H(D) atoms per formula unit as a solid solution. All hydrides and deuterides crystallize in the NaZn13-type cubic structure with the lattice parameter increasing linearly with H(D) concentration. The H(D) absorption enhances the Curie temperature significantly. The magnetic entropy change of the highly H-absorbed compound La(Fe0.91Si0.09)(13)H-1.81 reaches similar to 26 J/kg.K under a magnetic field change of 5 T near the Curie temperature T-C = 350 K. No observable isotope effect seems to imply that only the magnetovolume effect is responsible for the strong interplay between magnetism and lattice. |
收录类别 | SCI |
资助信息 | National Basic Research Program of China (973 Program) [2010CB833102]; Chinese Academy of Sciences; National Natural Science Foundation of China [10974244, 11004204] |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/39542] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Wang, ZC,He, LH,Cuevas, F,et al. Hydrogenation, structure and magnetic properties of La(Fe0.91Si0.09)(13) hydrides and deuterides[J]. CHINESE PHYSICS B,2011,20(6). |
APA | Wang, ZC,He, LH,Cuevas, F,Latroche, M,Shen, J,&Wang, FW.(2011).Hydrogenation, structure and magnetic properties of La(Fe0.91Si0.09)(13) hydrides and deuterides.CHINESE PHYSICS B,20(6). |
MLA | Wang, ZC,et al."Hydrogenation, structure and magnetic properties of La(Fe0.91Si0.09)(13) hydrides and deuterides".CHINESE PHYSICS B 20.6(2011). |
入库方式: OAI收割
来源:物理研究所
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