Improved Li-Storage Performance of Li4Ti5O12 Coated with C?N Compounds Derived from Pyrolysis of Urea through a Low-Temperature Approach
文献类型:期刊论文
作者 | Pan, HL ; Zhao, L ; Hu, YS ; Li, H ; Chen, LQ |
刊名 | CHEMSUSCHEM
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出版日期 | 2012 |
卷号 | 5期号:3页码:526 |
关键词 | LITHIUM-ION BATTERIES ELECTRODE MATERIALS CARBON NITROGEN ANODE INTERCALATION COMPOSITE 2-PHASE SPINEL FILMS |
ISSN号 | 1864-5631 |
通讯作者 | Hu, YS: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, POB 603, Beijing 100190, Peoples R China. |
中文摘要 | A uniform and thin amorphous layer of a C?N compound was coated on porous Li4Ti5O12 by pyrolysis of urea on its surface at a rather low temperature of 400 degrees C in an Ar atmosphere. Such a CN coating layer greatly improved the electrochemical performance of Li4Ti5O12. After coating, Li4Ti5O12 showed good rate and excellent cycling performance. Reversible capacities for the coated sample of 134 and 105 mAhg-1 were obtained at current rates of 5C and 10C, respectively, in the voltage range of 12.2 V, which is approximately two and five times higher than those of pristine Li4Ti5O12 at the same current rates. Excellent capacity retention of 95.8?% was achieved for the coated sample after 2000 cycles in a half cell at a 2C rate. |
收录类别 | SCI |
资助信息 | 863 Project [2009AA033101]; "973" Projects [2007CB936500, 2010CB833102]; NSFC [50972164]; CAS [KJCX2-YW-W26]; Science and Technology Planning Project of Guangdong Province, P.R. China [2010A090602001] |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/39654] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Pan, HL,Zhao, L,Hu, YS,et al. Improved Li-Storage Performance of Li4Ti5O12 Coated with C?N Compounds Derived from Pyrolysis of Urea through a Low-Temperature Approach[J]. CHEMSUSCHEM,2012,5(3):526. |
APA | Pan, HL,Zhao, L,Hu, YS,Li, H,&Chen, LQ.(2012).Improved Li-Storage Performance of Li4Ti5O12 Coated with C?N Compounds Derived from Pyrolysis of Urea through a Low-Temperature Approach.CHEMSUSCHEM,5(3),526. |
MLA | Pan, HL,et al."Improved Li-Storage Performance of Li4Ti5O12 Coated with C?N Compounds Derived from Pyrolysis of Urea through a Low-Temperature Approach".CHEMSUSCHEM 5.3(2012):526. |
入库方式: OAI收割
来源:物理研究所
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