Ion transport in polyacrylonitrile-based electrolytes with high LiTFSI contents
文献类型：期刊论文
| 作者 | Wang, ZX ; Gao, WD ; Huang, XJ ; Mo, YJ ; Chen, LQ |
| 刊名 | ELECTROCHEMICAL AND SOLID STATE LETTERS
 |
| 出版日期 | 2001 |
| 卷号 | 4期号:9页码:A148 |
| 关键词 | IN-SALT ELECTROLYTES POLYMER ELECTROLYTES LI+ IONS CONDUCTIVITY |
| ISSN号 | 1099-0062 |
| 通讯作者 | Wang, ZX: Chinese Acad Sci, Inst Phys, Lab Solid State Ion, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | The evolution of the microstructures in polymer electrolytes composed of propylene carbonate (PC), polyacrylonitrile (PAN), and lithium bis(trifluoromethane sulfone imide) (LiTFSI) has been characterized by Raman spectroscopy and the conduction behaviors of the electrolytes have been evaluated by ac impedance spectroscopy. The conductivity of the electrolyte depends strongly on the association of the lithium ions and ion clusters with the electron donor of the polymer. A transition from "salt-in-polymer" to "polymer-in-salt" electrolyte has been observed when the salt content is very high (PC:PAN:LiTFSI = 1:1:5). Based on these facts, the distinct roles of the polymer are proposed on the transportation of the ionic species in conventional "salt-in-polymer" electrolyte and in "polymer-in-salt" electrolytes. (C) 2001 The Electrochemical Society. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-18 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/40370]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, ZX,Gao, WD,Huang, XJ,et al. Ion transport in polyacrylonitrile-based electrolytes with high LiTFSI contents[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS,2001,4(9):A148. |
| APA | Wang, ZX,Gao, WD,Huang, XJ,Mo, YJ,&Chen, LQ.(2001).Ion transport in polyacrylonitrile-based electrolytes with high LiTFSI contents.ELECTROCHEMICAL AND SOLID STATE LETTERS,4(9),A148. |
| MLA | Wang, ZX,et al."Ion transport in polyacrylonitrile-based electrolytes with high LiTFSI contents".ELECTROCHEMICAL AND SOLID STATE LETTERS 4.9(2001):A148. |
入库方式： OAI收割
来源：物理研究所
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