Li-storage in LiFe1/4Mn1/4Co1/4Ni1/4PO4 solid solution
文献类型：期刊论文
| 作者 | Wang, XJ ; Yu, XQ ; Li, H ; Yang, XQ ; McBreen, J ; Huang, XJ |
| 刊名 | ELECTROCHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2008 |
| 卷号 | 10期号:9页码:1347 |
| 关键词 | CHEMICAL DIFFUSION-COEFFICIENT LITHIUM BATTERIES HYDROTHERMAL SYNTHESIS ELECTRODE MATERIALS OLIVINES LIFEPO4 CATHODES LIMPO4 MN FE |
| ISSN号 | 1388-2481 |
| 通讯作者 | Huang, XJ: Chinese Acad Sci, Inst Phys, Zhongguancun S 3rd St, Beijing 100190, Peoples R China. |
| 中文摘要 | Olivine structured LiFe1/4Mn1/4Co1/4Ni1/4PO4 in pure solid solution single phase was obtained using solid-state reaction. For the carbon-coated material, in a voltage range of 3.0-5.1 V (vs. Li/Li+), three voltage plateaus were observed clearly in both galvanostatic discharging and galvanostatic intermittent titration technique (GITT) curves. These three plateaus are corresponding to Co3+/Co2+, Mn3+/Mn2+ and Fe3+/Fe2+ redox couples. No definite plateau can be assigned to Ni3+/Ni2+ redox couple in this voltage range. The overpotentials show the maximum when the redox reaction shifts from one redox couple to another couple. The apparent chemical diffusion coefficients of lithium ((D) over bar (Li)) are in the same order of magnitude 10(-15) cm(2) s(-1) for all transition reactions. (C) 2008 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 资助信息 | Nature Scientific Foundation of China [50730005, 60621061]; BNL; U. S. Department of Energy [DEAC02-98CH10886] |
| 语种 | 英语 |
| 公开日期 | 2013-09-18 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/40893]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, XJ,Yu, XQ,Li, H,et al. Li-storage in LiFe1/4Mn1/4Co1/4Ni1/4PO4 solid solution[J]. ELECTROCHEMISTRY COMMUNICATIONS,2008,10(9):1347. |
| APA | Wang, XJ,Yu, XQ,Li, H,Yang, XQ,McBreen, J,&Huang, XJ.(2008).Li-storage in LiFe1/4Mn1/4Co1/4Ni1/4PO4 solid solution.ELECTROCHEMISTRY COMMUNICATIONS,10(9),1347. |
| MLA | Wang, XJ,et al."Li-storage in LiFe1/4Mn1/4Co1/4Ni1/4PO4 solid solution".ELECTROCHEMISTRY COMMUNICATIONS 10.9(2008):1347. |
入库方式： OAI收割
来源：物理研究所
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