Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties
文献类型：期刊论文
| 作者 | Han, HB ; Zhou, SS ; Zhang, DJ ; Feng, SW ; Li, LF ; Liu, K ; Feng, WF ; Nie, J ; Li, H ; Huang, XJ ; Armand, M ; Zhou, ZB |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2011 |
| 卷号 | 196期号:7页码:3623 |
| 关键词 | PROPYLENE CARBONATE ALUMINUM CORROSION POLYMER BATTERIES TEMPERATURE STABILITY GRAPHITE LIPF6 DECOMPOSITION INSERTION BEHAVIOR |
| ISSN号 | 0378-7753 |
| 通讯作者 | Nie, J: Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, 1037 Luoyu Rd, Wuhan 430074, Peoples R China. |
| 中文摘要 | Lithium bis(fluorosulfonyl)imide (LiFSI) has been studied as conducting salt for lithium-ion batteries, in terms of the physicochemical and electrochemical properties of the neat LiFSI salt and its nonaqueous liquid electrolytes. Our pure LiFSI salt shows a melting point at 145 degrees C, and is thermally stable up to 200 degrees C. It exhibits far superior stability towards hydrolysis than LiPF(6). Among the various lithium salts studied at the concentration of 1.0 M (= mol dm(-3)) in a mixture of ethylene carbonate (EC)/ethyl methyl carbonate (EMC) (3:7, v/v), LiFSI shows the highest conductivity in the order of LiFSI > LiPF(6) > Li[N(SO(2)CF(3))(2)] (LiTFSI) > LiClO(4) > LiBF(4). The stability of Al in the high potential region (3.0-5.0V vs. Li(+)/Li) has been confirmed for high purity LiFSI-based electrolytes using cyclic voltammetry, SEM morphology, and chronoamperometry, whereas Al corrosion indeed occurs in the LiFSI-based electrolytes tainted with trace amounts of LiCl (50 ppm). With high purity, LiFSI outperforms LiPF6 in both Li/LiCoO(2) and graphite/LiCoO(2) cells. (C) 2010 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [50873041]; National High Technology Research and Development Program of China [2007AA03Z246]; State Key Laboratory of Materials Processing, Die and Mould Technology, Huazhong University of Science and Technology |
| 语种 | 英语 |
| 公开日期 | 2013-09-18 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/40899]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Han, HB,Zhou, SS,Zhang, DJ,et al. Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties[J]. JOURNAL OF POWER SOURCES,2011,196(7):3623. |
| APA | Han, HB.,Zhou, SS.,Zhang, DJ.,Feng, SW.,Li, LF.,...&Zhou, ZB.(2011).Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties.JOURNAL OF POWER SOURCES,196(7),3623. |
| MLA | Han, HB,et al."Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties".JOURNAL OF POWER SOURCES 196.7(2011):3623. |
入库方式： OAI收割
来源：物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。