Li-Ti-O compounds and carbon-coated Li-Ti-O compounds as anode materials for lithium ion batteries
文献类型:期刊论文
作者 | Shu, J |
刊名 | ELECTROCHIMICA ACTA
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出版日期 | 2009 |
卷号 | 54期号:10页码:2869 |
关键词 | THERMAL-STABILITY ELEVATED-TEMPERATURES LITHIATED GRAPHITE ELECTROLYTE INSERTION LI2TI3O7 INTERCALATION MECHANISM SOLVENTS CATHODE |
ISSN号 | 0013-4686 |
通讯作者 | Shu, J: Harbin Inst Technol, Dept Appl Chem, Harbin 150001, Peoples R China. |
中文摘要 | Intrinsic structure stability of Li(4)Ti(5)O(12), Li(2)TiO(3) and Li(2)Ti(3)O(7) is confirmed by XRD in the broad electrochemical range (0.0-5.0V versus Li/Li(+)). It is clearly that all the Li-Ti-O ternary compounds can accommodate lithium ions in their crystal structures. Attributed to the stable framework all these Li-Ti-O, compounds show excellent cycle calendar life. One drawback to date for these compounds is the poor kinetic behaviors result from low electronic conductivity. Carbon coating is a kind of effective method for improvement. Comparing with carbon free Li-Ti-O ternary compounds, it is obvious that thermal stability, cyclability and reversible specific capacity are obviously enhanced with carbon coating. After many cycles, large reversible capacities approximate 224 mAh g(-1) (50 cycles), 90 mAh g(-1) (50 cycles) and 219 mAh g(-1) (27 cycles) are delivered for Li(4)Ti(5)O(12)/C, Li(2)TiO(3)/C and Li(2)Ti(3)O(7)/C, respectively. (C) 2008 Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-18 |
源URL | [http://ir.iphy.ac.cn/handle/311004/40911] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Shu, J. Li-Ti-O compounds and carbon-coated Li-Ti-O compounds as anode materials for lithium ion batteries[J]. ELECTROCHIMICA ACTA,2009,54(10):2869. |
APA | Shu, J.(2009).Li-Ti-O compounds and carbon-coated Li-Ti-O compounds as anode materials for lithium ion batteries.ELECTROCHIMICA ACTA,54(10),2869. |
MLA | Shu, J."Li-Ti-O compounds and carbon-coated Li-Ti-O compounds as anode materials for lithium ion batteries".ELECTROCHIMICA ACTA 54.10(2009):2869. |
入库方式: OAI收割
来源:物理研究所
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