Mesoporous silicas of hierarchical structure by hydrothermal surfactant-templating under mild alkali conditions
文献类型：期刊论文
| 作者 | Yuan, ZY ; Zhou, WZ ; Su, BL ; Peng, LM |
| 刊名 | NANOPOROUS MATERIALS III
 |
| 出版日期 | 2002 |
| 卷号 | 141页码:133 |
| 关键词 | MOLECULAR-SIEVE MCM-41 CURVED SHAPES MECHANISM MORPHOGENESIS NANOTUBES PATTERNS SYSTEMS SPHERES FIBERS |
| ISSN号 | 0167-2991 |
| 通讯作者 | Yuan, ZY: Fac Univ Notre Dame Paix, ISIS, Lab Inorgan Mat Chem, 61 Rue Bruxelles, B-5000 Namur, Belgium. |
| 中文摘要 | Mesoporous silicas with hierarchical structures were synthesized under a mild alkali condition by cationic or mixed cationic-nonionic surfactant templating. When cetylpyridium bromide was used, a novel morphology of mesoporous silica of type MCM-41 was formed. It was obsearved. that single nanotubes with diameter of about 5 nm and bundles of nanotubes grew from the (001) surface of the mesoporous silica particles, forming a paintbrush-like morphology. The synthesis process was investigated and the formation mechanism of such a surface nanotube patterning is discussed. When mixed surfactant of cetylpyridium chloride and Triton X-100 was used, a mixed ordered-disordered hierarchical mesostructure with arc rings of submicrometer scales was observed in the synthesized mesoporous silica which exhibits a narrow pore size distribution, high surface area and a large pore volume. Are ropes consisting of ordered mesopores, as well as many spheres of submicrometer in diameter with shells of about 40 nm in thickness consisting of ordered arrays of mesopores, were observed, though the majority of the particles contained disordered mesoporous microdomains. This material lacks overall long-range ordering whereas local ordering of mesopores exists. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-18 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/41908]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan, ZY,Zhou, WZ,Su, BL,et al. Mesoporous silicas of hierarchical structure by hydrothermal surfactant-templating under mild alkali conditions[J]. NANOPOROUS MATERIALS III,2002,141:133. |
| APA | Yuan, ZY,Zhou, WZ,Su, BL,&Peng, LM.(2002).Mesoporous silicas of hierarchical structure by hydrothermal surfactant-templating under mild alkali conditions.NANOPOROUS MATERIALS III,141,133. |
| MLA | Yuan, ZY,et al."Mesoporous silicas of hierarchical structure by hydrothermal surfactant-templating under mild alkali conditions".NANOPOROUS MATERIALS III 141(2002):133. |
入库方式： OAI收割
来源：物理研究所
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