METAL VAPOR SYNTHESIS OF AIR-SENSITIVE TRANSITION-METAL FULLERIDES - EVIDENCE OF IR-SPECTRA
文献类型：期刊论文
| 作者 | ZHOA, W ; LI, YX ; CHEN, LQ ; LIU, ZJ ; HUANG, YZ ; ZHAO, ZX |
| 刊名 | SOLID STATE COMMUNICATIONS
 |
| 出版日期 | 1994 |
| 卷号 | 92期号:4页码:313 |
| 关键词 | SOLID C-60 FILMS X = 0 THIN-FILMS DOPED C-60 MODES C60 SUPERCONDUCTIVITY SURFACES RAMAN AXC60 |
| ISSN号 | 0038-1098 |
| 通讯作者 | ZHOA, W: CHINESE ACAD SCI,INST PHYS,POB 603,BEIJING 100080,PEOPLES R CHINA. |
| 中文摘要 | By metal vapor synthesis, we found the first evidence that Sn, In and Au could react with C60 forming a kind of bulk metal fullerides. IR transmission spectra revealed that the M(x)C60 films (M = In, Sn and Au) showed new air-sensitive bands at about 1451, 1389 and 486 cm-1 besides the lines of pristine C60. As the black M(x)C60 films exposed to the air, they turned into the color of C60 film and these air-sensitive bands vanished meanwhile two new bands appeared at approximately 3590 cm-1 and approximately 552 cm-1. The absorbance near 550 cm-1 increased slightly. The conversion of 1451 cm-1 line into 1428 cm-1 line, the Raman spectra and the UV-visible absorption spectra indicated that the cage of C60 does not disrupt in M(x)C60 films. With reference to the reported results of the EPR and photoelectron spectroscopy, these fullerides were tentatively assigned to the complexes of M(x)C60. We found that the metal vapor synthesis is a powerful method to prepare various metal fullerides in which the metal may be of large cohesive energy and high boiling point. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-18 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/41919]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | ZHOA, W,LI, YX,CHEN, LQ,et al. METAL VAPOR SYNTHESIS OF AIR-SENSITIVE TRANSITION-METAL FULLERIDES - EVIDENCE OF IR-SPECTRA[J]. SOLID STATE COMMUNICATIONS,1994,92(4):313. |
| APA | ZHOA, W,LI, YX,CHEN, LQ,LIU, ZJ,HUANG, YZ,&ZHAO, ZX.(1994).METAL VAPOR SYNTHESIS OF AIR-SENSITIVE TRANSITION-METAL FULLERIDES - EVIDENCE OF IR-SPECTRA.SOLID STATE COMMUNICATIONS,92(4),313. |
| MLA | ZHOA, W,et al."METAL VAPOR SYNTHESIS OF AIR-SENSITIVE TRANSITION-METAL FULLERIDES - EVIDENCE OF IR-SPECTRA".SOLID STATE COMMUNICATIONS 92.4(1994):313. |
入库方式： OAI收割
来源：物理研究所
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