Molecular Engineering of the Glass Transition: Glass-Forming Ability across a Homologous Series of Cyclic Stilbenes
文献类型：期刊论文
| 作者 | Ping, W ; Paraska, D ; Baker, R ; Harrowell, P ; Angell, CA |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2011 |
| 卷号 | 115期号:16页码:4696 |
| 关键词 | THERMODYNAMIC ASPECTS WEIGHT DEPENDENCE LIQUIDS TEMPERATURES POLYMERS DYNAMICS ISOMERS ALLOYS |
| ISSN号 | 1520-6106 |
| 通讯作者 | Harrowell, P: Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia. |
| 中文摘要 | We report on the glass-forming abilities of the homologous series 1,2-diphenylcyclo-butene, pentene, hexene and heptene a series that retains the cis-phenyl configuration characteristic of the well glass former, o-terphenyl. We find that the glass forming ability shows a sharp maximum for the, six-membered ring and demonstrate that this trend in glass forming ability is a consequence of a maximum, for the 1, 2-diphenylcyclohexene, of the reduced glass transition temperature T(g)/T(m). Since the nonmonotonic trend in T(g)/T(m) is entirely due to variations in T(m), we conclude that the design target for maximizing the glass forming ability across an homologous series should focus on the crystal stability and the factors that determine it. |
| 收录类别 | SCI |
| 资助信息 | Australian Research Council |
| 语种 | 英语 |
| 公开日期 | 2013-09-18 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/42259]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ping, W,Paraska, D,Baker, R,et al. Molecular Engineering of the Glass Transition: Glass-Forming Ability across a Homologous Series of Cyclic Stilbenes[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2011,115(16):4696. |
| APA | Ping, W,Paraska, D,Baker, R,Harrowell, P,&Angell, CA.(2011).Molecular Engineering of the Glass Transition: Glass-Forming Ability across a Homologous Series of Cyclic Stilbenes.JOURNAL OF PHYSICAL CHEMISTRY B,115(16),4696. |
| MLA | Ping, W,et al."Molecular Engineering of the Glass Transition: Glass-Forming Ability across a Homologous Series of Cyclic Stilbenes".JOURNAL OF PHYSICAL CHEMISTRY B 115.16(2011):4696. |
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来源：物理研究所
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