Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template
文献类型:期刊论文
作者 | Zhang, HR ; Shen, CM ; Chen, ST ; Xu, ZC ; Liu, FS ; Li, JQ ; Gao, HJ |
刊名 | NANOTECHNOLOGY
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出版日期 | 2005 |
卷号 | 16期号:2页码:267 |
关键词 | HOLLOW SPHERES OXIDE NANOPARTICLES NANOCRYSTALS CRYSTALS GROWTH ROUTE SHAPE CUO |
ISSN号 | 0957-4484 |
通讯作者 | Gao, HJ: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China. |
中文摘要 | Hollow polyhedra and cubes of nanostructured Cu2O particles have been synthesized by reduction of CuSO4 with ascorbate acid in the solution phase. The nanostructures were obtained when the cetyltrimethylammonium (CTAB) concentration ranged from 0 to 0.03 M in the presence of NaOH. Structural characterizations, by means of x-ray photoelectron spectroscopy (XPS) for measuring Cu valence states and by electron microscopy for microstructure and chemical analyses, suggest that most Cu2O nanoparticles are covered with a thin CuO shell arising possibly from reaction of the adsorbed oxygen on the Cu2O particle surface. The blue shift is observed as microstructures of Cu2O nanoparticles changed from cubic to hollow in ultraviolet and visible (UV-visible) absorption spectra. Both the Cu2O hollow and cubic nanostructures show certain quantum-confined effects. A cationic CTAB template mechanism is proposed to interpret the formation of the Cu2O nanoparticles. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-18 |
源URL | [http://ir.iphy.ac.cn/handle/311004/42315] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang, HR,Shen, CM,Chen, ST,et al. Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template[J]. NANOTECHNOLOGY,2005,16(2):267. |
APA | Zhang, HR.,Shen, CM.,Chen, ST.,Xu, ZC.,Liu, FS.,...&Gao, HJ.(2005).Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template.NANOTECHNOLOGY,16(2),267. |
MLA | Zhang, HR,et al."Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template".NANOTECHNOLOGY 16.2(2005):267. |
入库方式: OAI收割
来源:物理研究所
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