中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template

文献类型:期刊论文

作者Zhang, HR ; Shen, CM ; Chen, ST ; Xu, ZC ; Liu, FS ; Li, JQ ; Gao, HJ
刊名NANOTECHNOLOGY
出版日期2005
卷号16期号:2页码:267
关键词HOLLOW SPHERES OXIDE NANOPARTICLES NANOCRYSTALS CRYSTALS GROWTH ROUTE SHAPE CUO
ISSN号0957-4484
通讯作者Gao, HJ: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China.
中文摘要Hollow polyhedra and cubes of nanostructured Cu2O particles have been synthesized by reduction of CuSO4 with ascorbate acid in the solution phase. The nanostructures were obtained when the cetyltrimethylammonium (CTAB) concentration ranged from 0 to 0.03 M in the presence of NaOH. Structural characterizations, by means of x-ray photoelectron spectroscopy (XPS) for measuring Cu valence states and by electron microscopy for microstructure and chemical analyses, suggest that most Cu2O nanoparticles are covered with a thin CuO shell arising possibly from reaction of the adsorbed oxygen on the Cu2O particle surface. The blue shift is observed as microstructures of Cu2O nanoparticles changed from cubic to hollow in ultraviolet and visible (UV-visible) absorption spectra. Both the Cu2O hollow and cubic nanostructures show certain quantum-confined effects. A cationic CTAB template mechanism is proposed to interpret the formation of the Cu2O nanoparticles.
收录类别SCI
语种英语
公开日期2013-09-18
源URL[http://ir.iphy.ac.cn/handle/311004/42315]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Zhang, HR,Shen, CM,Chen, ST,et al. Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template[J]. NANOTECHNOLOGY,2005,16(2):267.
APA Zhang, HR.,Shen, CM.,Chen, ST.,Xu, ZC.,Liu, FS.,...&Gao, HJ.(2005).Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template.NANOTECHNOLOGY,16(2),267.
MLA Zhang, HR,et al."Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template".NANOTECHNOLOGY 16.2(2005):267.

入库方式: OAI收割

来源:物理研究所

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