The inquiry of liquids and glass transition by heat capacity
文献类型:期刊论文
作者 | Ke, HB ; Wen, P ; Wang, WH |
刊名 | AIP ADVANCES
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出版日期 | 2012 |
卷号 | 2期号:4 |
关键词 | FORMING MOLECULAR LIQUIDS SUPERCOOLED LIQUIDS NEUTRON-SCATTERING LOW-TEMPERATURES O-TERPHENYL WATER RELAXATION MODELS ICE HETEROGENEITY |
ISSN号 | 2158-3226 |
通讯作者 | Ke, HB (reprint author), Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China. |
中文摘要 | Reconsidering the intrinsic connection between simple liquids and the glass transition, we attempt to understand them with an explicit liquid model. Liquids are defined to the mixture composed of tiny particles restricted in non-identical potential energy wells, where translational motions of tiny particles in statistical equilibrium, as well as vibrations and rotations, are distinguished. The liquid model offers an opportunity to build up a quantitative correlation between heat capacity and the basic motions appearing in liquids. Agreements between theoretical prediction and experimental data on heat capacities of typical simple liquids are reached. A serial of experimental data confirm that the glass transition originates from the falling out-of-equilibrium of the translational motions in liquids. The work might provide a novel and intuitive way to uncover a shady corner of the mysterious liquids and the glass transition. Copyright 2012 Author(s). This article is distributed under a Creative Commons Attribution 3.0 Unported License. [http://dx.doi.org/10.1063/1.4773224] |
收录类别 | SCI |
资助信息 | Science Foundation of China [51071170, 50921091]; MOST 973 of China [2010CB731603]; Chinese Academy of Science |
语种 | 英语 |
公开日期 | 2013-09-23 |
源URL | [http://ir.iphy.ac.cn/handle/311004/45260] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Ke, HB,Wen, P,Wang, WH. The inquiry of liquids and glass transition by heat capacity[J]. AIP ADVANCES,2012,2(4). |
APA | Ke, HB,Wen, P,&Wang, WH.(2012).The inquiry of liquids and glass transition by heat capacity.AIP ADVANCES,2(4). |
MLA | Ke, HB,et al."The inquiry of liquids and glass transition by heat capacity".AIP ADVANCES 2.4(2012). |
入库方式: OAI收割
来源:物理研究所
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