The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping
文献类型:期刊论文
作者 | Zhang, WY ; Yu, HC ; Zhao, YG ; Zhang, XP ; Shi, YG ; Cheng, ZH ; Li, JQ |
刊名 | JOURNAL OF PHYSICS-CONDENSED MATTER
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出版日期 | 2004 |
卷号 | 16期号:28页码:4935 |
关键词 | THERMOELECTRIC-POWER PHYSICAL-PROPERTIES NACO2O4 THERMOPOWER NAXCO2O4 SYSTEM OXIDES SODIUM |
ISSN号 | 0953-8984 |
通讯作者 | Zhao, YG (reprint author), Tsing Hua Univ, Dept Phys, Beijing 100084, Peoples R China. |
中文摘要 | Structure, transport and magnetic properties have been investigated for the layered materials NagammaCo(1-x)Mn(x)O(2) (0 less than or equal to x less than or equal to 0.5). With increase of the Mn concentration, the in-plane lattice parameter a decreases while the lattice parameter c increases. 3% Mn doping can result in a metal-insulator transition. The temperature dependence of the magnetization of the samples obeys the Curie-Weiss law and the effective moment of the magnetic ions increases with doping. Electron energy-loss spectroscopy measurement shows that the Co valence is about 3.3 and remains unchanged upon doping. However, the valence of Mn increases rapidly with doping and reaches 3.7 +/- 0.1 for the sample with x = 0.5. The results are discussed in terms of the disorder effect induced by doping of magnetic ions. This work demonstrates that the structure, transport and magnetic properties of NagammaCoO2 are very sensitive to doping with magnetic ions. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-23 |
源URL | [http://ir.iphy.ac.cn/handle/311004/45326] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang, WY,Yu, HC,Zhao, YG,et al. The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2004,16(28):4935. |
APA | Zhang, WY.,Yu, HC.,Zhao, YG.,Zhang, XP.,Shi, YG.,...&Li, JQ.(2004).The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping.JOURNAL OF PHYSICS-CONDENSED MATTER,16(28),4935. |
MLA | Zhang, WY,et al."The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping".JOURNAL OF PHYSICS-CONDENSED MATTER 16.28(2004):4935. |
入库方式: OAI收割
来源:物理研究所
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