中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping

文献类型:期刊论文

作者Zhang, WY ; Yu, HC ; Zhao, YG ; Zhang, XP ; Shi, YG ; Cheng, ZH ; Li, JQ
刊名JOURNAL OF PHYSICS-CONDENSED MATTER
出版日期2004
卷号16期号:28页码:4935
关键词THERMOELECTRIC-POWER PHYSICAL-PROPERTIES NACO2O4 THERMOPOWER NAXCO2O4 SYSTEM OXIDES SODIUM
ISSN号0953-8984
通讯作者Zhao, YG (reprint author), Tsing Hua Univ, Dept Phys, Beijing 100084, Peoples R China.
中文摘要Structure, transport and magnetic properties have been investigated for the layered materials NagammaCo(1-x)Mn(x)O(2) (0 less than or equal to x less than or equal to 0.5). With increase of the Mn concentration, the in-plane lattice parameter a decreases while the lattice parameter c increases. 3% Mn doping can result in a metal-insulator transition. The temperature dependence of the magnetization of the samples obeys the Curie-Weiss law and the effective moment of the magnetic ions increases with doping. Electron energy-loss spectroscopy measurement shows that the Co valence is about 3.3 and remains unchanged upon doping. However, the valence of Mn increases rapidly with doping and reaches 3.7 +/- 0.1 for the sample with x = 0.5. The results are discussed in terms of the disorder effect induced by doping of magnetic ions. This work demonstrates that the structure, transport and magnetic properties of NagammaCoO2 are very sensitive to doping with magnetic ions.
收录类别SCI
语种英语
公开日期2013-09-23
源URL[http://ir.iphy.ac.cn/handle/311004/45326]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Zhang, WY,Yu, HC,Zhao, YG,et al. The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2004,16(28):4935.
APA Zhang, WY.,Yu, HC.,Zhao, YG.,Zhang, XP.,Shi, YG.,...&Li, JQ.(2004).The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping.JOURNAL OF PHYSICS-CONDENSED MATTER,16(28),4935.
MLA Zhang, WY,et al."The metal-insulator transition in the strongly correlated layered compound Na gamma CoO2 induced by dilute Mn doping".JOURNAL OF PHYSICS-CONDENSED MATTER 16.28(2004):4935.

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来源:物理研究所

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