Ultrasonic field induced chiral symmetry breaking of NaClO3 crystallization
文献类型：期刊论文
| 作者 | Song, YT ; Chen, WC ; Chen, XL |
| 刊名 | CRYSTAL GROWTH & DESIGN
 |
| 出版日期 | 2008 |
| 卷号 | 8期号:5页码:1448 |
| 关键词 | SOLID-PHASE HOMOCHIRALITY STIRRED CRYSTALLIZATION POSSIBLE TRANSITION PRIMARY NUCLEATION SODIUM-CHLORATE ICE SONOCRYSTALLISATION CAVITATION CONVECTION |
| ISSN号 | 1528-7483 |
| 通讯作者 | Chen, XL (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | It is found that chiral symmetry breaking can be achieved in NaClO3 crystallization under an ultrasonic field, with a large crystal enantiomeric excess (mean values > 0.967) in almost every crystallization, and complete chiral symmetry breaking can be realized by seed inducing under the ultrasonic field. The chirality propagating process through secondary nucleation originating from an initial nucleus or a seed can be directly observed, and this large enantiomeric excess can be explained through secondary nucleation induced by the cavitation of the ultrasonic field and a recycling process. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-23 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/46350]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Song, YT,Chen, WC,Chen, XL. Ultrasonic field induced chiral symmetry breaking of NaClO3 crystallization[J]. CRYSTAL GROWTH & DESIGN,2008,8(5):1448. |
| APA | Song, YT,Chen, WC,&Chen, XL.(2008).Ultrasonic field induced chiral symmetry breaking of NaClO3 crystallization.CRYSTAL GROWTH & DESIGN,8(5),1448. |
| MLA | Song, YT,et al."Ultrasonic field induced chiral symmetry breaking of NaClO3 crystallization".CRYSTAL GROWTH & DESIGN 8.5(2008):1448. |
入库方式： OAI收割
来源：物理研究所
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