Vibrational spectroscopic study on ion solvation and ion association of lithium tetrafluoroborate in 4-ethoxymethyl-ethylene carbonate
文献类型：期刊论文
| 作者 | Qiao, HW ; Luan, HL ; Zhou, ZM ; Fang, XP ; Yao, W ; Wang, X ; Li, JM |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2008 |
| 卷号 | 26期号:4页码:689 |
| ISSN号 | 1001-604X |
| 中文摘要 | Solvation and association interactions in solutions of lithium tetrafluoroborate/4-ethoxymethyl-ethylene carbonate (EEC) have been studied as a function of concentration of lithium tetrafluoroborate by infrared and Raman spectroscopy. Strong interactions between Li(+) and solvent molecules or BF(4)(-) anions were observed. Splitting of the ring symmetric angle deformation band, the carbonyl stretching band and the skeletal ring vibrational band suggests that the interaction between Li(+) ions and EEC molecules take place via the oxygen atom on the carbonyl group. The apparent solvation numbers of Li(+), varying from 4.32 to 1.26 with increasing the solution concentrations, were deduced. Band-fitting to the B-F stretching band of BF(4)(-) anion permits detailed assess of ion pairing. The spectroscopically free BF(4)(-) anion, contact ion pair and contact ion dimmers coexist in concentrated solutions. |
| 收录类别 | SCI |
| 公开日期 | 2013-09-23 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/46535]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qiao, HW,Luan, HL,Zhou, ZM,et al. Vibrational spectroscopic study on ion solvation and ion association of lithium tetrafluoroborate in 4-ethoxymethyl-ethylene carbonate[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(4):689. |
| APA | Qiao, HW.,Luan, HL.,Zhou, ZM.,Fang, XP.,Yao, W.,...&Li, JM.(2008).Vibrational spectroscopic study on ion solvation and ion association of lithium tetrafluoroborate in 4-ethoxymethyl-ethylene carbonate.CHINESE JOURNAL OF CHEMISTRY,26(4),689. |
| MLA | Qiao, HW,et al."Vibrational spectroscopic study on ion solvation and ion association of lithium tetrafluoroborate in 4-ethoxymethyl-ethylene carbonate".CHINESE JOURNAL OF CHEMISTRY 26.4(2008):689. |
入库方式： OAI收割
来源：物理研究所
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