Visible-light-assisted degradation of dye pollutants over Fe(III)-loaded resin in the presence of H2O2 at neutral pH values
文献类型:期刊论文
作者 | Cheng, MM ; Ma, WH ; Li, J ; Huang, YP ; Zhao, JC |
刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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出版日期 | 2004 |
卷号 | 38期号:5页码:1569 |
关键词 | PHOTO-FENTON DEGRADATION HYDROGEN-PEROXIDE ORGANIC POLLUTANTS WASTE-WATER PHOTODEGRADATION PREOXIDATION IRRADIATION RADIATION OXIDATION REAGENT |
ISSN号 | 0013-936X |
通讯作者 | Zhao, JC (reprint author), Chinese Acad Sci, Inst Chem, Lab Photochem, Ctr Mol Sci, Beijing 100080, Peoples R China. |
中文摘要 | A novel catalyst was synthesized by direct exchange of ferric ions onto a cationic resin (Amberlite IRA200). Upon visible light irradiation (lambda > 420 nm) in the presence of H2O2, this catalyst was found to be highly effective for the degradation of nonbiodegradable cationic dyes, Malachite green, Rhodamine 13, and Methylene blue, even at neutral pH values. It was also easy to separate from the degraded solution. By total organic carbon, FT-IR, and GC-MS analysis, the degradation process of Malachite green was shown to proceed with demethylation and phenyl ring openings into CO2 and small molecular compounds. EPR studies revealed that (OH)-O-. radicals, other than (OOH)-O-./O-2(.-), were involved as the active species. A possible reaction mechanism is proposed on the basis of all the information obtained under various experimental conditions. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-23 |
源URL | [http://ir.iphy.ac.cn/handle/311004/46557] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Cheng, MM,Ma, WH,Li, J,et al. Visible-light-assisted degradation of dye pollutants over Fe(III)-loaded resin in the presence of H2O2 at neutral pH values[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2004,38(5):1569. |
APA | Cheng, MM,Ma, WH,Li, J,Huang, YP,&Zhao, JC.(2004).Visible-light-assisted degradation of dye pollutants over Fe(III)-loaded resin in the presence of H2O2 at neutral pH values.ENVIRONMENTAL SCIENCE & TECHNOLOGY,38(5),1569. |
MLA | Cheng, MM,et al."Visible-light-assisted degradation of dye pollutants over Fe(III)-loaded resin in the presence of H2O2 at neutral pH values".ENVIRONMENTAL SCIENCE & TECHNOLOGY 38.5(2004):1569. |
入库方式: OAI收割
来源:物理研究所
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