X-ray diffraction and vibrational spectroscopic studies on PAN-LiTFSI polymer electrolytes
文献类型：期刊论文
| 作者 | Li, JZ ; Huang, XJ ; Chen, LQ |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 2000 |
| 卷号 | 147期号:7页码:2653 |
| 关键词 | POLY(ETHYLENE OXIDE) CONDUCTIVITY BEHAVIOR IONIC INTERACTIONS GEL ELECTROLYTES LITHIUM SALT LICF3SO3 COORDINATION LIN(CF3SO2)2 PLASTICIZER TRANSPORT |
| ISSN号 | 0013-4651 |
| 通讯作者 | Li, JZ (reprint author), Chinese Acad Sci, Inst Phys, Lab Solid State Ion, Beijing 100080, Peoples R China. |
| 中文摘要 | Polyacrylonitrile(PAN)-lithium bis(trifluoromethane sulfone)imide (LiTFSI) complex has been investigated by X-ray diffraction (XRD) and vibrational spectroscopy Two kinds of amorphous complexes are found in the salt-in-polymer and polymer-in-salt regime, respectively. Phase transition is observed by XRD as the content of lithium salt increases from P(AN)(6)-LiTFSI to P(AN)(2)-LiTFSI. It is also evidenced by Fourier Transform infrared (FTIR) and Raman spectroscopic studies. Interactions between the Li ion and host polymer are clarified by comparing the spectral evolution of the -C=N group before and after LiTFSI was complexed with PAN. However, the LiTFSI addition has no obvious influence on the -CH2 group of PAN, evidently different from that observed with PEO. Li+ ions coordinate also with O and/or N of anions, probed by the spectral changes of -SNS and -SO2 groups. (C) 2000 The Electrochemical Society. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-23 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/46692]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li, JZ,Huang, XJ,Chen, LQ. X-ray diffraction and vibrational spectroscopic studies on PAN-LiTFSI polymer electrolytes[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2000,147(7):2653. |
| APA | Li, JZ,Huang, XJ,&Chen, LQ.(2000).X-ray diffraction and vibrational spectroscopic studies on PAN-LiTFSI polymer electrolytes.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,147(7),2653. |
| MLA | Li, JZ,et al."X-ray diffraction and vibrational spectroscopic studies on PAN-LiTFSI polymer electrolytes".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 147.7(2000):2653. |
入库方式： OAI收割
来源：物理研究所
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