New observations on the formation of "row-nucleated" structures of isotactic polystyrene
文献类型：期刊论文
| 作者 | Gu, FM ; Bu, HS ; Zhang, Z |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2000 |
| 卷号 | 33期号:15页码:5490 |
| 关键词 | CONFORMATION GELS CRYSTALLIZATION HOMOGENEITY GELATION BEHAVIOR |
| ISSN号 | 0024-9297 |
| 通讯作者 | Gu, FM (reprint author), Hiroshima Univ, Venture Business Lab, 2-313 Kagamiyama, Hiroshima 7398527, Japan. |
| 中文摘要 | A unique 60 degrees C endothermic peak was found in the differential scanning calorimetry (DSC) measurement of freeze-dried isotactic polystyrene (i-PS) prepared from a 0.01 wt % benzene solution. While i-PS was melted before preparing a solution at a temperature beyond the equilibrium melting point, nothing could be observed around 60 degrees C. The endotherm can be attributed to the melting of microgel crystals. Morphology observation revealed that ribbonlike films of i-PS were formed when the solution was spread on a cold water surface. After isothermal crystallization of the films, "row-nucleated" crystals were grossly produced without any extensional deformation of molecular chains. It is suggested that microgel crystals may act as heterogeneous species to initiate the growth of "row-nucleated" crystals. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/49856]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gu, FM,Bu, HS,Zhang, Z. New observations on the formation of "row-nucleated" structures of isotactic polystyrene[J]. MACROMOLECULES,2000,33(15):5490. |
| APA | Gu, FM,Bu, HS,&Zhang, Z.(2000).New observations on the formation of "row-nucleated" structures of isotactic polystyrene.MACROMOLECULES,33(15),5490. |
| MLA | Gu, FM,et al."New observations on the formation of "row-nucleated" structures of isotactic polystyrene".MACROMOLECULES 33.15(2000):5490. |
入库方式： OAI收割
来源：物理研究所
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