中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Observation of superconductivity at 30 similar to 46K in A(x)Fe(2)Se(2) (A=Li, Na, Ba, Sr, Ca, Yb, and Eu)

文献类型:期刊论文

作者Ying, TP ; Chen, XL ; Wang, G ; Jin, SF ; Zhou, TT ; Lai, XF ; Zhang, H ; Wang, WY
刊名SCIENTIFIC REPORTS
出版日期2012
卷号2
关键词MOLYBDENUM-DISULFIDE PHASE-SEPARATION METAL INTERCALATION AMMONIA ORDER C-60
ISSN号2045-2322
通讯作者Chen, XL (reprint author), Chinese Acad Sci, Res & Dev Ctr Funct Crystals, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China.
中文摘要New iron selenide superconductors by intercalating smaller-sized alkali metals (Li, Na) and alkaline earths using high-temperature routes have been pursued ever since the discovery of superconductivity at about 30 K in KFe2Se2, but all have failed so far. Here we demonstrate that a series of superconductors with enhanced T-c=30 similar to 46 K can be obtained by intercalating metals, Li, Na, Ba, Sr, Ca, Yb, and Eu in between FeSe layers by the ammonothermal method at room temperature. Analysis on their powder X-ray diffraction patterns reveals that all the main phases can be indexed based on body-centered tetragonal lattices with a similar to 3.755-3.831 angstrom while c similar to 15.99-20.54 angstrom. Resistivities show the corresponding sharp transitions at 45 K and 39 K for NaFe2Se2 and Ba0.8Fe2Se2, respectively, confirming their bulk superconductivity. These findings provide a new starting point for studying the properties of these superconductors and an effective synthetic route for the exploration of new superconductors as well.
收录类别SCI
资助信息National Science Foundation of China [90922037, 51072226]; Chinese Academy of Sciences
语种英语
公开日期2013-09-24
源URL[http://ir.iphy.ac.cn/handle/311004/50180]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Ying, TP,Chen, XL,Wang, G,et al. Observation of superconductivity at 30 similar to 46K in A(x)Fe(2)Se(2) (A=Li, Na, Ba, Sr, Ca, Yb, and Eu)[J]. SCIENTIFIC REPORTS,2012,2.
APA Ying, TP.,Chen, XL.,Wang, G.,Jin, SF.,Zhou, TT.,...&Wang, WY.(2012).Observation of superconductivity at 30 similar to 46K in A(x)Fe(2)Se(2) (A=Li, Na, Ba, Sr, Ca, Yb, and Eu).SCIENTIFIC REPORTS,2.
MLA Ying, TP,et al."Observation of superconductivity at 30 similar to 46K in A(x)Fe(2)Se(2) (A=Li, Na, Ba, Sr, Ca, Yb, and Eu)".SCIENTIFIC REPORTS 2(2012).

入库方式: OAI收割

来源:物理研究所

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