Optoelectronic characteristics of single CdS nanobelts
文献类型:期刊论文
作者 | Li, QH ; Gao, T ; Wang, TH |
刊名 | APPLIED PHYSICS LETTERS
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出版日期 | 2005 |
卷号 | 86期号:19 |
关键词 | CADMIUM SULFIDE CRYSTALS ELECTRONIC TRANSPORT THIN-FILMS NANOWIRES PHOTOCONDUCTIVITY IMPERFECTIONS |
ISSN号 | 0003-6951 |
通讯作者 | Wang, TH (reprint author), Hunan Univ, MicroNano Technol Res Ctr, Changsha 410082, Peoples R China. |
中文摘要 | Superparamagnetic Fe3O4 nanocrystals were prepared by a chemical coprecipitation method with a thin thickness-adjustable silica layer coated on the surface by hydrolysis of tetraethyl orthosilicate. The silica-coated Fe3O4 nanocrystals were well dispersed and consisted of a 6-7 nm diameter magnetic core and a silica shell about 2 nm thick, according to transmission electron microscopy observations. Fourier transform infrared spectra revealed that amino (-NH2) groups were successfully covalently bonded to the silica-coated Fe3O4 and then carboxyl (-COOH) groups were functionalized to the surface through the reaction of -NH2 and glutaric anhydride. The synthesized nanocrystals have a cubic spinel structure as characterized by x-ray diffraction, electron diffraction and high-resolution transmission electron microscopy. Their magnetic properties were carefully investigated by a SQUID magnetometer. The results showed that the nanocrystals were superparamagnetic and the blocking temperature TB shifted from 131 K down to 92 K after they were coated with a thin nonmagnetic layer, since this layer can effectively suppress the magnetic dipolar interaction between particles; the chemically inert silica layer can limit the outside environment effect on the Fe3O4 cores quite well due to the excellent magnetic reproducibility of the coated nanocrystals after ageing for 7 months at room temperature. In addition, the dependence of their high-field specific magnetization on temperature has a T-2 relationship. These functionalized silica-coated Fe3O4 superparamagnetic nanocrystals have great potential in biomagnetic applications. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/50412] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Li, QH,Gao, T,Wang, TH. Optoelectronic characteristics of single CdS nanobelts[J]. APPLIED PHYSICS LETTERS,2005,86(19). |
APA | Li, QH,Gao, T,&Wang, TH.(2005).Optoelectronic characteristics of single CdS nanobelts.APPLIED PHYSICS LETTERS,86(19). |
MLA | Li, QH,et al."Optoelectronic characteristics of single CdS nanobelts".APPLIED PHYSICS LETTERS 86.19(2005). |
入库方式: OAI收割
来源:物理研究所
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