Photo Retro-Diels-Alder Reactions
文献类型：期刊论文
| 作者 | Johns, VK ; Shi, Z ; Dang, W ; McInnis, MD ; Weng, YX ; Liao, Y |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2011 |
| 卷号 | 115期号:28页码:8093 |
| 关键词 | THIN-FILM TRANSISTORS PENTACENE PRECURSOR ANTHRACENE DERIVATIVES CYCLOREVERSION POLYACETYLENE DIENOPHILES ROUTE |
| ISSN号 | 1089-5639 |
| 通讯作者 | Liao, Y (reprint author), Univ Cent Florida, Dept Chem, Orlando, FL 32816 USA. |
| 中文摘要 | Photo-retro-Diels-Alder (PrDA) reactions of a variety of Diels-Alder (DA) adducts were studied. Experimental results showed that the photoreactivity (quantum yield) depends on the electron-donating ability of the cliene component and the electron-withdrawing ability of the dienophile component. The mechanism was studied by trapping the reaction intermediate, O(2) quenching, time-resolved absorption, and fluorescence spectroscopy. All the results support a mechanism that involves a charge-separated intermediate generated from a singlet excited state. The PrDA reaction may find applications in photoresponsive materials, photolithography, drug delivery, and mechanistic research. |
| 收录类别 | SCI |
| 资助信息 | Air Force Office of Scientic Research |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/50894]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Johns, VK,Shi, Z,Dang, W,et al. Photo Retro-Diels-Alder Reactions[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2011,115(28):8093. |
| APA | Johns, VK,Shi, Z,Dang, W,McInnis, MD,Weng, YX,&Liao, Y.(2011).Photo Retro-Diels-Alder Reactions.JOURNAL OF PHYSICAL CHEMISTRY A,115(28),8093. |
| MLA | Johns, VK,et al."Photo Retro-Diels-Alder Reactions".JOURNAL OF PHYSICAL CHEMISTRY A 115.28(2011):8093. |
入库方式： OAI收割
来源：物理研究所
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