RECENT DEVELOPMENTS IN RARE-EARTH NITRIDES AND CARBIDES
文献类型:期刊论文
| 作者 | HADJIPANAYIS, GC ; ZHENG, YH ; MURTHY, AS ; GONG, W ; YANG, FM |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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| 出版日期 | 1995 |
| 卷号 | 222页码:49 |
| 关键词 | MAGNETIC-PROPERTIES |
| ISSN号 | 0925-8388 |
| 通讯作者 | HADJIPANAYIS, GC (reprint author), UNIV DELAWARE,DEPT PHYS & ASTRON,NEWARK,DE 19716, USA. |
| 中文摘要 | In this article, we review our recent studies on new rare-earth intermetallic compounds including the Ga, Si substituted 2:17-type compounds, their nitrides and carbides, and the Sm-3(Fe,Ti)(29)N-5 compounds. Much of our recent work has been focused predominantly in the Sm-2(Fe,Ga)(17)C-x alloys, where we used melt-spinning and subsequent annealing to obtain a high coercivity. The highest coercivity obtained so far was in Sm2Fe14Ga3C2.5, with a value of 12.8 kOe at room temperature. The off-stoichiometric Sm2Fe14-xCoxSi2Ny nitrides maintain the ThZZn17-type structure but with a unit-cell expansion Delta V/V up to 5% compared to the host materials. The Sm2Fe14-xCoxSi2C2 carbides maintain the Th2Zn17-type structure when z=1 and transform to BaCd11-type structure when z=2. A very large anisotropy field with H-a value of 227 kOe for Sm2Fe14Si2N26 and 276 kOe for Sm2Fe10Co4Si2N2.3, is observed at low temperature (1.5 K). The Sm-3(Fe,Ti)(29)N-5 compound and its nitrides show very interesting magnetic properties. Both of these compounds exhibit ferromagnetic ordering with T-c of 486 and 750 K, respectively. The room-temperature saturation magnetization is 119 e.m.u. g(-1) for the parent compounds and 145 e.m.u. g(-1) for the nitrides. The easy-magnetization direction changes from planar to uniaxial upon nitrogenation. The anisotropy field for the nitrides is 12 T at room temperature and 25 T at 4.2 K. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/51924] ![]() |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | HADJIPANAYIS, GC,ZHENG, YH,MURTHY, AS,et al. RECENT DEVELOPMENTS IN RARE-EARTH NITRIDES AND CARBIDES[J]. JOURNAL OF ALLOYS AND COMPOUNDS,1995,222:49. |
| APA | HADJIPANAYIS, GC,ZHENG, YH,MURTHY, AS,GONG, W,&YANG, FM.(1995).RECENT DEVELOPMENTS IN RARE-EARTH NITRIDES AND CARBIDES.JOURNAL OF ALLOYS AND COMPOUNDS,222,49. |
| MLA | HADJIPANAYIS, GC,et al."RECENT DEVELOPMENTS IN RARE-EARTH NITRIDES AND CARBIDES".JOURNAL OF ALLOYS AND COMPOUNDS 222(1995):49. |
入库方式: OAI收割
来源:物理研究所
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