Selective nontemplated adsorption of organic molecules on nanofacets and the role of bonding patterns
文献类型:期刊论文
作者 | Du, SX ; Gao, HJ ; Seidel, C ; Tsetseris, L ; Ji, W ; Kopf, H ; Chi, LF ; Fuchs, H ; Pennycook, SJ ; Pantelides, ST |
刊名 | PHYSICAL REVIEW LETTERS
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出版日期 | 2006 |
卷号 | 97期号:15 |
关键词 | EPITAXY SURFACES CHEMISORPTION NANOPARTICLES NANOCRYSTALS PTCDA DNA |
ISSN号 | 0031-9007 |
通讯作者 | Gao, HJ (reprint author), Chinese Acad Sci, Inst Phys, Natl Lab Condensed Matter Phys, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | A key element of functionalizing nanocrystals with organic molecules is the nontemplated selective adsorption of different molecules on different facets. Here we report scanning-tunneling-microscopy images of perylene-3,4,9,10-tetracarboxylic-dianhydride and 2,5-dimethyl-N,N-'-dicyanoquinonediimine on silver, demonstrating selective adsorption on different facets. We also report first-principles calculations that account for the data and show that bonding, which controls selectivity, occurs via the end atoms, while the molecule's midregion arches away from the substrate. The results are also consistent with data that have been interpreted in terms of bonding via the midregion. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/52386] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Du, SX,Gao, HJ,Seidel, C,et al. Selective nontemplated adsorption of organic molecules on nanofacets and the role of bonding patterns[J]. PHYSICAL REVIEW LETTERS,2006,97(15). |
APA | Du, SX.,Gao, HJ.,Seidel, C.,Tsetseris, L.,Ji, W.,...&Pantelides, ST.(2006).Selective nontemplated adsorption of organic molecules on nanofacets and the role of bonding patterns.PHYSICAL REVIEW LETTERS,97(15). |
MLA | Du, SX,et al."Selective nontemplated adsorption of organic molecules on nanofacets and the role of bonding patterns".PHYSICAL REVIEW LETTERS 97.15(2006). |
入库方式: OAI收割
来源:物理研究所
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