Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity
文献类型:期刊论文
作者 | Liu, J ; Chen, XL ; Wang, WJ ; Liu, Y ; Huang, QS ; Guo, ZP |
刊名 | CRYSTENGCOMM
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出版日期 | 2011 |
卷号 | 13期号:10页码:3425 |
关键词 | PHOTOCATALYTIC ACTIVITY NANOCRYSTALS OXIDE NANOBELTS ARRAYS PSEUDOPOTENTIALS FABRICATION NUCLEATION NANOSHEETS NANOSCALE |
ISSN号 | 1466-8033 |
通讯作者 | Chen, XL (reprint author), Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China. |
中文摘要 | In this work, we demonstrate a simple gas-phase process to synthesize ZnO with exposed reactive {0001} facets without the use of any capping agent. The method is based on controlling the ZnO growth direction, causing it to switch from the typical [0001] to [10 (1) over bar0], resulting in [10 (1) over bar0] grown nanowhiskers with exposed reactive {0001} facets. Moreover, these nanowhiskers self-assemble on ZnO hollow spheres to form a three-dimensional hierarchical nanostructure, which stabilizes these nanowhiskers against agglomeration. Such a designed ZnO nanostructure endows the ZnO sensing material with both small crystal sizes and exposed reactive {0001} facets, which leads to greatly enhanced gas sensitivities compared to typical [0001] grown ZnO nanowires. Such reactive-facet-enhanced gas sensitivity is also shown by our calculation of the chemisorption energy of oxygen, based on density functional theory. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/52411] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Liu, J,Chen, XL,Wang, WJ,et al. Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity[J]. CRYSTENGCOMM,2011,13(10):3425. |
APA | Liu, J,Chen, XL,Wang, WJ,Liu, Y,Huang, QS,&Guo, ZP.(2011).Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity.CRYSTENGCOMM,13(10),3425. |
MLA | Liu, J,et al."Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity".CRYSTENGCOMM 13.10(2011):3425. |
入库方式: OAI收割
来源:物理研究所
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