中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity

文献类型:期刊论文

作者Liu, J ; Chen, XL ; Wang, WJ ; Liu, Y ; Huang, QS ; Guo, ZP
刊名CRYSTENGCOMM
出版日期2011
卷号13期号:10页码:3425
关键词PHOTOCATALYTIC ACTIVITY NANOCRYSTALS OXIDE NANOBELTS ARRAYS PSEUDOPOTENTIALS FABRICATION NUCLEATION NANOSHEETS NANOSCALE
ISSN号1466-8033
通讯作者Chen, XL (reprint author), Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China.
中文摘要In this work, we demonstrate a simple gas-phase process to synthesize ZnO with exposed reactive {0001} facets without the use of any capping agent. The method is based on controlling the ZnO growth direction, causing it to switch from the typical [0001] to [10 (1) over bar0], resulting in [10 (1) over bar0] grown nanowhiskers with exposed reactive {0001} facets. Moreover, these nanowhiskers self-assemble on ZnO hollow spheres to form a three-dimensional hierarchical nanostructure, which stabilizes these nanowhiskers against agglomeration. Such a designed ZnO nanostructure endows the ZnO sensing material with both small crystal sizes and exposed reactive {0001} facets, which leads to greatly enhanced gas sensitivities compared to typical [0001] grown ZnO nanowires. Such reactive-facet-enhanced gas sensitivity is also shown by our calculation of the chemisorption energy of oxygen, based on density functional theory.
收录类别SCI
语种英语
公开日期2013-09-24
源URL[http://ir.iphy.ac.cn/handle/311004/52411]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Liu, J,Chen, XL,Wang, WJ,et al. Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity[J]. CRYSTENGCOMM,2011,13(10):3425.
APA Liu, J,Chen, XL,Wang, WJ,Liu, Y,Huang, QS,&Guo, ZP.(2011).Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity.CRYSTENGCOMM,13(10),3425.
MLA Liu, J,et al."Self-assembly of [10(1)over-bar0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity".CRYSTENGCOMM 13.10(2011):3425.

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来源:物理研究所

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