Spatial imaging of individual vibronic states in the interior of single molecules
文献类型:期刊论文
作者 | Huan, Q ; Jiang, Y ; Zhang, YY ; Ham, U ; Ho, W |
刊名 | JOURNAL OF CHEMICAL PHYSICS
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出版日期 | 2011 |
卷号 | 135期号:1 |
关键词 | SCANNING TUNNELING MICROSCOPE VIBRATIONAL SPECTROSCOPY ELECTRON-TRANSPORT JUNCTIONS SPECTRA FILMS C-60 |
ISSN号 | 0021-9606 |
通讯作者 | Ho, W (reprint author), Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA. |
中文摘要 | Selective excitations of specific vibronic modes in position space are realized in single naphthalocyanine molecules adsorbed on an ultrathin alumina film by a scanning tunneling microscope at low temperature. Distinct spatial distributions are imaged for the different vibronic modes, which are in accordance with spectra recorded over different points of the molecule and its orbital structure. These distinct vibronic images, together with the differential conductance images and calculated molecular orbitals, lead to vibrational excitations that are associated with the doubly degenerate lowest unoccupied molecular orbitals (LUMO) - LUMO-alpha and LUMO-beta. These results reveal the presence of different molecular conformations on the surface and the nature of the electron-vibrational coupling. (C) 2011 American Institute of Physics. [doi:10.1063/1.3598958] |
收录类别 | SCI |
资助信息 | National Science Foundation (NSF) [DMR-0606520] |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/52804] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Huan, Q,Jiang, Y,Zhang, YY,et al. Spatial imaging of individual vibronic states in the interior of single molecules[J]. JOURNAL OF CHEMICAL PHYSICS,2011,135(1). |
APA | Huan, Q,Jiang, Y,Zhang, YY,Ham, U,&Ho, W.(2011).Spatial imaging of individual vibronic states in the interior of single molecules.JOURNAL OF CHEMICAL PHYSICS,135(1). |
MLA | Huan, Q,et al."Spatial imaging of individual vibronic states in the interior of single molecules".JOURNAL OF CHEMICAL PHYSICS 135.1(2011). |
入库方式: OAI收割
来源:物理研究所
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