Stability and flexibility of self-assembled monolayers of thiols consisting of a horizontal large pi-system and a vertical spacer
文献类型：期刊论文
| 作者 | Dou, RF ; Ma, XC ; Xi, L ; Yip, HL ; Wong, KY ; Lau, WM ; Fan, XL ; Jia, JF ; Xue, QK ; Yang, WS ; Ma, H ; Jen, AKY |
| 刊名 | JOURNAL OF PHYSICS-CONDENSED MATTER
 |
| 出版日期 | 2008 |
| 卷号 | 20期号:31 |
| 关键词 | STACKING-INTERACTIONS AB-INITIO GOLD POLYMORPHISM DIMER |
| ISSN号 | 0953-8984 |
| 通讯作者 | Lau, WM (reprint author), Chinese Univ Hong Kong, Dept Phys & Mat Sci, Shatin, Hong Kong, Peoples R China. |
| 中文摘要 | Self-assembled monolayers (SAMs) of (4-mercaptophenyl) (10-nitro-9-anthryl) acetylene (MPNAA) on Au(111) are studied with scanning tunneling microscopy (STM). Through careful analysis of the bias-dependent sub-molecular features observed in the high-resolution STM images, important structural details of the MPNAA SAM are disclosed, in addition to its structural character common for the anthracene-based thiol SAMs studied in a recent paper (Dou et al 2006 Langmuir 22 3049). With these experimental results, a new model is proposed for the SAM structure to explain, particularly, the molecule-substrate, molecule-molecule and intramolecular interactions, as well as their competitions and compromises in the formation of the SAM structure. Flexibilities and application potentials of the SAMs of thiols based on a long pi-system (like that of anthracene or even pentacene) arranged horizontally and a vertical spacer (like the phenyl-acetylene group) are also discussed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/53011]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Dou, RF,Ma, XC,Xi, L,et al. Stability and flexibility of self-assembled monolayers of thiols consisting of a horizontal large pi-system and a vertical spacer[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2008,20(31). |
| APA | Dou, RF.,Ma, XC.,Xi, L.,Yip, HL.,Wong, KY.,...&Jen, AKY.(2008).Stability and flexibility of self-assembled monolayers of thiols consisting of a horizontal large pi-system and a vertical spacer.JOURNAL OF PHYSICS-CONDENSED MATTER,20(31). |
| MLA | Dou, RF,et al."Stability and flexibility of self-assembled monolayers of thiols consisting of a horizontal large pi-system and a vertical spacer".JOURNAL OF PHYSICS-CONDENSED MATTER 20.31(2008). |
入库方式： OAI收割
来源：物理研究所
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