Strong nodeless pairing on separate electron Fermi surface sheets in (Tl, K)Fe1.78Se2 probed by ARPES
文献类型:期刊论文
作者 | Wang, XP ; Qian, T ; Richard, P ; Zhang, P ; Dong, J ; Wang, HD ; Dong, CH ; Fang, MH ; Ding, H |
刊名 | EPL
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出版日期 | 2011 |
卷号 | 93期号:5 |
关键词 | RESOLVED PHOTOEMISSION-SPECTROSCOPY SUPERCONDUCTING GAPS BA0.6K0.4FE2AS2 |
ISSN号 | 0295-5075 |
通讯作者 | Wang, XP (reprint author), Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China. |
中文摘要 | To improve the optoelectronic properties of iron oxide as a photoelectrode, hematite (alpha-Fe2O3) thin films were doped with titanium using atmospheric pressure chemical vapor deposition (APCVD) for synthesis. The films were prepared by pyrolysis of Fe(CO)(5) and TiCl4 precursors on fluorine-doped tin oxide (FTO) substrates and found to have a polycrystalline morphology with faceted particulates similar to 20 to 50 nm in size with a preferred crystallographic growth along the [110] direction. The performance of the photoanodes was measured as a function of titanium concentration. A maximum efficiency was observed at similar to 0.8 atom% Ti in hematite. The Incident Photon-to-current Conversion Efficiency (IPCE) to hydrogen was measured in alkaline electrolyte. Under an applied bias of 0.6 V vs. Ag/AgCl at 400 nm the IPCE for water splitting in alkaline solution was found to be 27.2%, the highest efficiency reported for Ti doped hematite photoanodes. The IPCEs of the photoanode thin films at lower applied bias were further increased by calcination at 500 degrees C and by use of glucose as an anolyte. |
收录类别 | SCI |
资助信息 | Chinese Academy of Sciences [2010Y1JB6]; National Basic Research (973) Program of China [2010CB923000, 2011CBA0010]; Nature Science Foundation of China [10974175, 11004232, 11050110422] |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/53163] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Wang, XP,Qian, T,Richard, P,et al. Strong nodeless pairing on separate electron Fermi surface sheets in (Tl, K)Fe1.78Se2 probed by ARPES[J]. EPL,2011,93(5). |
APA | Wang, XP.,Qian, T.,Richard, P.,Zhang, P.,Dong, J.,...&Ding, H.(2011).Strong nodeless pairing on separate electron Fermi surface sheets in (Tl, K)Fe1.78Se2 probed by ARPES.EPL,93(5). |
MLA | Wang, XP,et al."Strong nodeless pairing on separate electron Fermi surface sheets in (Tl, K)Fe1.78Se2 probed by ARPES".EPL 93.5(2011). |
入库方式: OAI收割
来源:物理研究所
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