Structural evolution induced by acceptor doping into BaTiO3 ceramics
文献类型：期刊论文
| 作者 | Wei, XK ; Zhang, QH ; Li, FY ; Jin, CQ ; Yu, RC |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2010 |
| 卷号 | 508期号:2页码:486 |
| 关键词 | MAGNETIC-PROPERTIES OXYGEN VACANCY DOPED BATIO3 FERROELECTRICITY FILM FERROMAGNETISM TEMPERATURE SITE IRON |
| ISSN号 | 0925-8388 |
| 通讯作者 | Yu, RC (reprint author), Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China. |
| 中文摘要 | Solid state reaction method is used to synthesize Ba(Tii-xTMx)O3-delta (TM = Fe, Mn and Co) and (Ba1-ySry)(Ti1/3Fe2/3)O3-delta ceramics. The X-ray diffraction, scanning electron microscopy and transmission electron microscopy investigations reveal that structural evolutions from an orthorhombic BaTiO3 to a hexagonal Ba(Ti1-xTMx)O3-delta, a hexagonal to a rhombohedral in Ba(Ti1-xMnx)O3-delta, and a hexagonal to a pseudo-cubic transition in (Ba1-ySry)(Ti1/3Fe2/3)O3-delta are induced by increasing the doping concentration. Due to the oxygen vacancies derived from acceptor doping, nanoscale domains of incommensurate modulation (ICM) resultant are commonly observed in the hexagonal Ba(Ti1-xTMx)O3-delta compounds. The newly discovered rhombohedral Ba(Ti1/3Mn2/3)O3-delta having characteristic of face-sharing prism corner-connected by oxygen atoms is a typical example in searching for novel multiferroics. Discrepancies between the ionic radii of the B- and A-site dopants and that of Ti and Ba as a function of the doping concentrations, i.e., the effects of oxygen vacancies and the electronic configurations of the dopants, are concluded to be the driving forces for the structural transitions. (c) 2010 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [10774168, 50921091]; Beijing Municipal Commission of Education |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/53305]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wei, XK,Zhang, QH,Li, FY,et al. Structural evolution induced by acceptor doping into BaTiO3 ceramics[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2010,508(2):486. |
| APA | Wei, XK,Zhang, QH,Li, FY,Jin, CQ,&Yu, RC.(2010).Structural evolution induced by acceptor doping into BaTiO3 ceramics.JOURNAL OF ALLOYS AND COMPOUNDS,508(2),486. |
| MLA | Wei, XK,et al."Structural evolution induced by acceptor doping into BaTiO3 ceramics".JOURNAL OF ALLOYS AND COMPOUNDS 508.2(2010):486. |
入库方式： OAI收割
来源：物理研究所
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