Structural modulation and magnetic properties of hexagonal Ba(Ti1-xFex)O3-delta ceramics
文献类型:期刊论文
作者 | Wei, XK ; Yao, LD ; Shen, X ; Yang, Y ; You, SJ ; Li, FY ; Jin, CQ ; Yu, RC |
刊名 | PHYSICA B-CONDENSED MATTER
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出版日期 | 2010 |
卷号 | 405期号:23页码:4851 |
关键词 | OXYGEN VACANCY DOPED BATIO3 FERROELECTRICITY MICROSTRUCTURE PEROVSKITE TRANSITION BEHAVIOR |
ISSN号 | 0921-4526 |
通讯作者 | Yu, RC (reprint author), Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China. |
中文摘要 | This paper investigates the structural and magnetic properties of hexagonal Ba(Ti1-xFex)O3-delta (x=0.3 and 0.7) ceramics, synthesized with solid-state reaction method. Transmission electron microscope investigations reveal that structural phase separation featured by non-modulated and modulated phases is identified by the electron diffraction patterns taken along [0 0 1] zone axis in x=0.3 sample (BTF30). While for x=0.7 sample (BTF70), a pure phase with commensurate and incommensurate modulations at different directions is identified. The superstructure peaks observed in their X-ray diffraction patterns are verified by their individual commensurate modulation, q(s)=1/2 (31-2) in the modulated phase of BTF30 and q(4,-1)=4/9(3 0 4)-(0 0 1) in BTF70. In addition to the room-temperature weak ferromagnetism of BTF30 and paramagnetism of BTF70, spin glass transitions with T-f=3.4 K for the former and T-f=33.6 K for the latter are observed. On the basis of the structural characteristics, the influence of O1 and O2 vacancies on magnetic and dielectric properties of the doped system is discussed. (C) 2010 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China [10774168, 50921091]; State Key Development Program for Basic Research of China [2005CB623602]; Beijing Municipal Commission of Education |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/53319] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Wei, XK,Yao, LD,Shen, X,et al. Structural modulation and magnetic properties of hexagonal Ba(Ti1-xFex)O3-delta ceramics[J]. PHYSICA B-CONDENSED MATTER,2010,405(23):4851. |
APA | Wei, XK.,Yao, LD.,Shen, X.,Yang, Y.,You, SJ.,...&Yu, RC.(2010).Structural modulation and magnetic properties of hexagonal Ba(Ti1-xFex)O3-delta ceramics.PHYSICA B-CONDENSED MATTER,405(23),4851. |
MLA | Wei, XK,et al."Structural modulation and magnetic properties of hexagonal Ba(Ti1-xFex)O3-delta ceramics".PHYSICA B-CONDENSED MATTER 405.23(2010):4851. |
入库方式: OAI收割
来源:物理研究所
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