Structural modulation in the orbitally induced Peierls state of MgTi(2)O(4)
文献类型:期刊论文
作者 | Yang, HX ; Zhu, BP ; Zeng, LJ ; Tian, HF ; Ma, C ; Shi, J ; Li, JQ |
刊名 | JOURNAL OF PHYSICS-CONDENSED MATTER
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出版日期 | 2008 |
卷号 | 20期号:27 |
关键词 | TRANSITION LIV2O4 SPINEL METAL |
ISSN号 | 0953-8984 |
通讯作者 | Li, JQ (reprint author), Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | The structural properties associated with the orbitally induced Peierls transition in MgTi(2)O(4) are characterized by in situ cooling TEM observations. A distinctive structural modulation with the wavevector of q(1) = 1/4 (0, 0, 4) has been well demonstrated below a critical temperature of about 260 K for MgTi(2)O(4). Systematic analysis demonstrates that this structural modulation can be well explained by an orbital order existing in the low-temperature insulating phase. It is also noted that the nonstoichiometric feature commonly appearing in the present system could yield visible changes in both physical and structural properties. A low-temperature study of the microstructure of Mg[Ti(1.9)Mg(0.1)]O(4) reveals that a little substitution of Mg(2+) for Ti(3+) ions on the octahedral sites can disrupt the long-range order of the t(2g) orbitals, resulting in complex tweed structures in the superstructure phase. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/53321] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Yang, HX,Zhu, BP,Zeng, LJ,et al. Structural modulation in the orbitally induced Peierls state of MgTi(2)O(4)[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2008,20(27). |
APA | Yang, HX.,Zhu, BP.,Zeng, LJ.,Tian, HF.,Ma, C.,...&Li, JQ.(2008).Structural modulation in the orbitally induced Peierls state of MgTi(2)O(4).JOURNAL OF PHYSICS-CONDENSED MATTER,20(27). |
MLA | Yang, HX,et al."Structural modulation in the orbitally induced Peierls state of MgTi(2)O(4)".JOURNAL OF PHYSICS-CONDENSED MATTER 20.27(2008). |
入库方式: OAI收割
来源:物理研究所
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