Structure and magnetic properties of a new single-molecule magnet [Mn11Fe1O12(CH3COO)(16)(H2O)(4)]center dot 2CH(3)COOH center dot 4H(2)O
文献类型：期刊论文
| 作者 | Cao, HB ; He, LH ; Wang, FW |
| 刊名 | CHINESE PHYSICS
 |
| 出版日期 | 2005 |
| 卷号 | 14期号:9页码:1892 |
| 关键词 | HIGH-SPIN MOLECULES MN-12 ACETATE RELAXATION NANOMAGNETS CRYSTAL |
| ISSN号 | 1009-1963 |
| 通讯作者 | Cao, HB (reprint author), Chinese Acad Sci, Inst Phys, State Key Lab Magnetism, POB 603, Beijing 100080, Peoples R China. |
| 中文摘要 | A new single-molecule magnet [Mn11Fe1O12(CH3COO)(16)(H2O)(4)]center dot 2CH(3)COOH center dot 4H(2)O (Mn11Fe1) has been synthesized. The structure has been studied by the single crystal x-ray diffraction, The difference of Jahn-Teller distortion between Fe3+ and Mn3+ ion reveals that Fe3+ ion substitutes for Mn3+ ion on the Mn(3) sites in the Mn-12 skeleton. The temperature dependence of the magnetization gives a blocking temperature T-B = 1.9K for Mn11Fe1. Based on the magnetization process analysis of the crystal at T=2K, we suggest that Mn11Fe1 has the ground state with a total spin S= 11/2. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/53446]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cao, HB,He, LH,Wang, FW. Structure and magnetic properties of a new single-molecule magnet [Mn11Fe1O12(CH3COO)(16)(H2O)(4)]center dot 2CH(3)COOH center dot 4H(2)O[J]. CHINESE PHYSICS,2005,14(9):1892. |
| APA | Cao, HB,He, LH,&Wang, FW.(2005).Structure and magnetic properties of a new single-molecule magnet [Mn11Fe1O12(CH3COO)(16)(H2O)(4)]center dot 2CH(3)COOH center dot 4H(2)O.CHINESE PHYSICS,14(9),1892. |
| MLA | Cao, HB,et al."Structure and magnetic properties of a new single-molecule magnet [Mn11Fe1O12(CH3COO)(16)(H2O)(4)]center dot 2CH(3)COOH center dot 4H(2)O".CHINESE PHYSICS 14.9(2005):1892. |
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来源：物理研究所
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