Structure Determination and Relative Properties of Novel Chiral Orthoborate KMgBO3
文献类型：期刊论文
| 作者 | Wu, L ; Sun, JC ; Zhang, Y ; Jin, SF ; Kong, YF ; Xu, JJ |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2010 |
| 卷号 | 49期号:6页码:2715 |
| 关键词 | INITIO STRUCTURE DETERMINATION NONLINEAR-OPTICAL PROPERTIES BORATES MM'(4)(BO3)(3) M CRYSTAL-STRUCTURE POWDER-DIFFRACTION COMPOUND NA SR M' |
| ISSN号 | 0020-1669 |
| 通讯作者 | Wu, L (reprint author), Nankai Univ, Sch Phys, MOE Key Lab Weak Light Nonlinear Photon, Tianjin 300071, Peoples R China. |
| 中文摘要 | A novel chiral orthoborate, KMgBO3, has been successfully synthesized via a standard solid-state reaction, and the crystal structure has been determined from powder X-ray diffraction data. It crystallizes in the cubic chiral space group P2(1)3. Isolated [BO3](3-) anionic groups, which are the fundamental building units, are distributed around the (111) crystallographic direction in an axial C-3 symmetry, and the configuration of O-3 planes is helical, similar to the aplanar ClO3 groups in NaClO3, which indicates an optical activity in it and is validated by the circular dichroism spectrum. The chiral feature of the borate is unique, and because of the noncentrosymmetric structure, the compound exhibits nonlinear optical properties, which are validated by second harmonic generation powder measurement. It has a wide transparency, including the vacuum ultraviolet region, The relations between the structures of KMgBO3 and NaClO3 and structural conversion form KMgBO3 to NaMgBO3 are also discussed. The ionic radii, interatomic distance, and the rigid tilting of BO3 groups are considered to be the main factors in the crystallization of different structures. |
| 收录类别 | SCI |
| 资助信息 | National Basic Research Program of China [2007CB307002]; Chinese National Key Basic Research Special Fund [2006CB921703]; Science Foundation of MOE for Doctoral Program [20070055096]; Natural Science Foundation of Tianjin [09JCYBJC02500]; National Natural Science Foundation of China [50902074, 90922037, 10774078]; International Centre for Diffraction Data (ICDD) |
| 语种 | 英语 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/53564]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu, L,Sun, JC,Zhang, Y,et al. Structure Determination and Relative Properties of Novel Chiral Orthoborate KMgBO3[J]. INORGANIC CHEMISTRY,2010,49(6):2715. |
| APA | Wu, L,Sun, JC,Zhang, Y,Jin, SF,Kong, YF,&Xu, JJ.(2010).Structure Determination and Relative Properties of Novel Chiral Orthoborate KMgBO3.INORGANIC CHEMISTRY,49(6),2715. |
| MLA | Wu, L,et al."Structure Determination and Relative Properties of Novel Chiral Orthoborate KMgBO3".INORGANIC CHEMISTRY 49.6(2010):2715. |
入库方式： OAI收割
来源：物理研究所
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