Study on the doped beta-FeSi2 obtained by metal vapor vacuum are ion source implantation and post-annealing
文献类型:期刊论文
作者 | Wang, SB ; Liang, H ; Zhu, PR |
刊名 | MATERIALS FOR ENERGY STORAGE, GENERATION AND TRANSPORT
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出版日期 | 2002 |
卷号 | 730页码:113 |
关键词 | STRUCTURAL-PROPERTIES BEAM SYNTHESIS ALPHA-FESI2 SI(111) PHASES FILMS |
ISSN号 | 0272-9172 |
通讯作者 | Wang, SB (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | Introducing cobalt into a Zn-P-O-amine system and using oxalates as starting materials, an amine containing open-framework cobalt zincophosphate, [C4N2H12][Co0.14Zn1.86(PO4)(H1.5PO4)(2)] (1), has been hydrothermally synthesized and structurally determined. It crystallizes in the monoclinic space group C2/c (No. 15) with cell parameters a = 13.374(3) Angstrom, b = 12.827(3) Angstrom, c = 8.1940(16) Angstrom, beta = 94.77(3)degrees, V = 1400.9(5) Angstrom(3), Z = 4, D-cal = 2.399 g cm(-3). The linkages of ZnO4 and PO4 give rise to four-membered rings, which serve as the secondary building unit for compound 1. The four-membered rings (four-MR) share their corners leading to chains. Connection of these chains results in a complex three-dimensional channel system. Eight-MR, twelve-MR and highly distorted twelve-MR channels can be observed along the [010], [110] and [101] directions, respectively. The prominent feature of compound 1 is the clover-like 16-MR channel along the [001] direction. The channel spaces are occupied by the diprotonated piperazine molecules with H-bonds to the framework. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/53854] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Wang, SB,Liang, H,Zhu, PR. Study on the doped beta-FeSi2 obtained by metal vapor vacuum are ion source implantation and post-annealing[J]. MATERIALS FOR ENERGY STORAGE, GENERATION AND TRANSPORT,2002,730:113. |
APA | Wang, SB,Liang, H,&Zhu, PR.(2002).Study on the doped beta-FeSi2 obtained by metal vapor vacuum are ion source implantation and post-annealing.MATERIALS FOR ENERGY STORAGE, GENERATION AND TRANSPORT,730,113. |
MLA | Wang, SB,et al."Study on the doped beta-FeSi2 obtained by metal vapor vacuum are ion source implantation and post-annealing".MATERIALS FOR ENERGY STORAGE, GENERATION AND TRANSPORT 730(2002):113. |
入库方式: OAI收割
来源:物理研究所
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