Superconductivity, structural features and charge ordering in NaxCoO2 center dot yH(2)O(0 <= y <= 1.8) system
文献类型:期刊论文
作者 | Yang, HX ; Shi, YG ; Xiao, RJ ; Liu, X ; Nie, CJ ; Li, JQ |
刊名 | SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
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出版日期 | 2005 |
卷号 | 6期号:7页码:740 |
关键词 | ELECTRON-DIFFRACTION PHASE-TRANSITIONS NA0.5COO2 OXIDES |
ISSN号 | 1468-6996 |
通讯作者 | Li, JQ (reprint author), Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100080, Peoples R China. |
中文摘要 | Structural and physical properties of NaxCoO2 and superconducting Na(x)CoO(2)center dot yH(2)O hydrates have been systematically investigated. Raman scattering measurements reveal that the five active phonons in NaxCoO2-yH(2)O System change systematically with the H2O intercalation and modification of superconductivity, in particular the A(1g) and E-1g modes in correlation with oxygen movements. Incoherent inelastic neutron scattering (IINS) study on the local structure of H2O-layers in NaxCoO2-yH(2)O (0 <= y <= 1.8) suggests the presence of three types of clusters, H3O+, H5O+ and ice-1h like weakly bonded water, among CoO2 sheets. Electron energy loss (EEL) analysis on Na0.33CoO2 center dot yH(2)O (0 <= y <= 1.3) indicates certain notable changes in the electronic structure during hydration. Microstructure and structural phase transitions accompanied with local atomic ordering in the charge-ordered phase Na0.5CoO2 have been investigated along with the hexagonal-orthorhombic phase transition. (c) 2005 Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-24 |
源URL | [http://ir.iphy.ac.cn/handle/311004/54098] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Yang, HX,Shi, YG,Xiao, RJ,et al. Superconductivity, structural features and charge ordering in NaxCoO2 center dot yH(2)O(0 <= y <= 1.8) system[J]. SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS,2005,6(7):740. |
APA | Yang, HX,Shi, YG,Xiao, RJ,Liu, X,Nie, CJ,&Li, JQ.(2005).Superconductivity, structural features and charge ordering in NaxCoO2 center dot yH(2)O(0 <= y <= 1.8) system.SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS,6(7),740. |
MLA | Yang, HX,et al."Superconductivity, structural features and charge ordering in NaxCoO2 center dot yH(2)O(0 <= y <= 1.8) system".SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS 6.7(2005):740. |
入库方式: OAI收割
来源:物理研究所
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